Chiral Group 4 Cyclopentadienyl Complexes and Their Use in Polymerization of Lactide Monomers

Chiral Group 4 Cyclopentadienyl Complexes and Their Use in Polymerization of Lactide Monomers

A family of group 4 alkoxide and aryloxide complexes of a chiral cyclopentadienyl-derived (hydro)permethylpentalenyl ligand (C8Me 6H; Pn*(H)) have been prepared and fully characterized. Both racemic and enantiopure complexes of all group 4 congeners were prepared with a wide variety of alkoxide and...

Полное описание

Библиографические подробности
Главные авторы:	Turner, Z, Buffet, J, O'Hare, D
Формат:	Journal article
Язык:	English
Опубликовано:	American Chemical Society 2014

Схожие документы

Group 4 permethylindenyl complexes for the polymerisation of L-, D- and rac-lactide monomers
по: Lamb, JV, и др.
Опубликовано: (2019)

Zirconocene alkoxides and aryloxides for the polymerization of L- and rac-lactide
по: Buffet, J-C, и др.
Опубликовано: (2016)

Constrained geometry scandium permethylindenyl complexes for the ring-opening polymerisation of l- and rac-lactide.
по: Diteepeng, N, и др.
Опубликовано: (2019)

l- and rac-lactide polymerisation using scandium and aluminium permethylindenyl complexes
по: Diteepeng, N, и др.
Опубликовано: (2020)

Ring-opening polymerisation of l- and rac-lactide using group 4 permethylpentalene aryloxides and alkoxides
по: Turner, ZR, и др.
Опубликовано: (2021)

Group 4 permethylindenyl constrained geometry complexes for ethylene polymerisation catalysis
по: Williams, T, и др.
Опубликовано: (2018)

Group 4 permethylindenyl complexes for slurry-phase polymerisation of ethylene
по: Lamb, J, и др.
Опубликовано: (2019)

Titanium and zirconium permethylpentalene complexes, Pn*MCpRX, as ethylene polymerization catalysts
по: Fraser, D, и др.
Опубликовано: (2016)

Switchable polymerization catalysis using a tin(II) catalyst and commercial monomers to toughen poly(L-lactide)
по: Yuntawattana, N, и др.
Опубликовано: (2021)

Heteroleptic Calcium Complexes Supported by a Phenoxy-Imine NON Ligand: Polymerization of Cyclic Esters by a Ligand-Assisted, Activated-Monomer Mechanism
по: Jones, RL, и др.
Опубликовано: (2024)

Group 4 constrained geometry complexes for olefin (co)polymerisation
по: Williams, TJ, и др.
Опубликовано: (2020)

Zirconium permethylpentalene amidinate complexes: characterization, bonding, and olefin polymerization catalysis
по: Robinson, TP, и др.
Опубликовано: (2022)

Electronic structures of mixed-sandwich complexes of cyclopentadienyl and Hydrotris(pyrazolyl)borate ligands with 3d transition metals.
по: Brunker, T, и др.
Опубликовано: (2003)

Early Transition Metal Permethylpentalene Complexes for the Polymerization of Ethylene
по: Chadwick, F, и др.
Опубликовано: (2014)

Ethylene polymerization using zirconocenes supported on pentafluorophenyl-modified solid polymethylaluminoxane
по: Lamb, JV, и др.
Опубликовано: (2020)

(eta 5-Cyclopentadienyl)(kappa 3-hydrotris(pyrazolyl)borate)cobalt(II)--the first high-spin cobalt organometallic complex.
по: Brunker, T, и др.
Опубликовано: (2001)

Sulfonamide-supported group 4 catalysts for the ring-opening polymerization of epsilon-caprolactone and rac-lactide.
по: Schwarz, A, и др.
Опубликовано: (2009)

Synthesis, structures, and redox properties of mixed-sandwich complexes of cyclopentadienyl and hydrotris(pyrazolyl)borate ligands with first-row transition metals
по: Brunker, T, и др.
Опубликовано: (2002)

Slurry-phase ethylene polymerisation using group 4 ansa-bridged permethylindenyl complexes supported on polymethylaluminoxane
по: Lamb, JV, и др.
Опубликовано: (2019)

Thermal stability of Group 6 bis(cyclopentadienyl) and ethylene bridged bis(cyclopentadienyl) monocarbonyl complexes; a theoretical study
по: Green, J, и др.
Опубликовано: (1999)

Sulfonamide-Supported Aluminum Catalysts for the Ring-Opening Polymerization of rac-Lactide
по: Schwarz, A, и др.
Опубликовано: (2010)

Slurry-phase ethylene polymerization using pentafluorophenyl- and pentafluorophenoxy-modified solid polymethylaluminoxanes
по: Kilpatrick, A, и др.
Опубликовано: (2017)

Polymerization of D,L-lactide in the presence of Boltorn™ polyester polyol
по: V. I. Gomzyak, и др.
Опубликовано: (2022-07-01)

Synthesis and reactivity of novel group 4 cyclopentadienyl amidinate imido compounds.
по: Guiducci, A, и др.
Опубликовано: (2000)

Synthesis and polymerization of metal-containing monomers /
по: 251630 Pomogailo, Anatoly D., и др.
Опубликовано: (1994)

Plasma polymerization of silicon-containing monomers
по: Talib, Zainal Abidin, и др.
Опубликовано: (2001)

Functional monomers : their preparation, polymerization, and application/
по: Yocum, Ronald H., и др.
Опубликовано: (1973)

Group 5 hydride and borohydride complexes supported by cyclopentadienyl-imido ligand sets.
по: McLeod, N, и др.
Опубликовано: (2014)

Sterically rigid bismuth pincer complexes; observation of the growing polymer chain in polar monomer polymerisation
по: Turner, ZR, и др.
Опубликовано: (2022)

PHOTOELECTRON STUDY OF ELECTRON-RICH IRON(I) CYCLOPENTADIENYL ARENE COMPLEXES AND OF THE RELATED IRON(II) CYCLOPENTADIENYL CYCLOHEXADIENYL COMPLEXES
по: Green, J, и др.
Опубликовано: (1983)

Lanthanide borohydride complexes supported by diaminobis(phenoxide) ligands for the polymerization of epsilon-caprolactone and L- and rac-lactide.
по: Bonnet, F, и др.
Опубликовано: (2005)

Selective Copolymerization from Mixed Monomers of Phthalic Anhydride, Propylene Oxide and Lactide Using Nano-Sized Zinc Glutarate
по: Xiaoting Zhang, и др.
Опубликовано: (2024-09-01)

Cyclopentadienyl, indenyl and bis(cyclopentadienyl) titanium imido compounds
по: Dunn, S, и др.
Опубликовано: (1997)

Cyclopentadienyl, indenyl and bis(cyclopentadienyl) titanium imido compounds
по: Dunn, S, и др.
Опубликовано: (1997)

II-cyclopentadienyl, n-arene, and related complexes /
по: 221318 Watts, W. E.

Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding
по: Kilpatrick, A, и др.
Опубликовано: (2017)

DFT Modeling of Coordination Polymerization of Polar Olefin Monomers by Molecular Metal Complexes
по: Yanan Zhao, и др.
Опубликовано: (2024-08-01)

Delamination of layered double hydroxides in polar monomers: new LDH-acrylate nanocomposites.
по: O'Leary, S, и др.
Опубликовано: (2002)

Synthesis of zirconocene complexes and their use in slurry-phase polymerisation of ethylene
по: Angpanitcharoen, P, и др.
Опубликовано: (2021)

Di-cyclopentadienyl-zinn/
по: 247961 Fischer, von E. O., и др.