Heterocycle-derived β-S-enals as bifunctional linchpins for the catalytic synthesis of saturated heterocycles

Heterocycle-derived β-S-enals as bifunctional linchpins for the catalytic synthesis of saturated heterocycles

We demonstrate how heterocycle-derived β-S-enals can be employed as bifunctional substrates in a cascade of two rhodium-catalysed C–C bond forming reactions to deliver substituted heterocyclic products. A single rhodium-catalyst, generated in situ from a commercial salt and ligand combination, is us...

Bibliográfalaš dieđut
Váldodahkkit:	Niu, J, Willis, M
Materiálatiipa:	Journal article
Almmustuhtton:	Royal Society of Chemistry 2016

Geahča maid

The development of catalytic methods for the synthesis of saturated nitrogen heterocycles
Dahkki: Chamberlain, A.E.R.
Almmustuhtton: (2020)

N‑Heterocyclic Carbene-Catalyzed Radical Reactions for Highly Enantioselective β‑Hydroxylation of Enals
Dahkki: Zhang, Yuexia, et al.
Almmustuhtton: (2016)

Part I: N-heterocyclic carbene catalyzed homoenolate addition of enals to nitroalkenes. Part II: Palladium catalyzed N-heterocyclic glycosides synthesis
Dahkki: Ji, Li
Almmustuhtton: (2015)

Tandem catalytic processes in heterocycle synthesis: Preparation of cinnolines
Dahkki: Ball, C, et al.
Almmustuhtton: (2012)

cis-Enals in N-heterocyclic carbene-catalyzed reactions : distinct stereoselectivity and reactivity
Dahkki: Chen, Xingkuan, et al.
Almmustuhtton: (2013)

Theoretical study of N-heterocyclic carbenes-catalyzed cascade annulation of benzodienones and enals
Dahkki: Sun, Hui, et al.
Almmustuhtton: (2013)

Enantioselective Stetter reactions of enals and modified chalcones catalyzed by N-heterocyclic carbenes
Dahkki: Fang, Xinqiang, et al.
Almmustuhtton: (2014)

Highly enantioselective addition of enals to isatin-derived ketimines catalyzed by N-heterocyclic carbenes : synthesis of spirocyclic γ-lactams
Dahkki: Lv, Hui, et al.
Almmustuhtton: (2013)

Access to spirocyclic oxindoles via N-heterocyclic carbene-catalyzed reactions of enals and oxindole-derived α,β-unsaturated imines
Dahkki: Jiang, Kun, et al.
Almmustuhtton: (2013)

Enantioselective Diels–Alder reactions of enals and alkylidene diketones catalyzed by N-heterocyclic carbenes
Dahkki: Fang, Xinqiang, et al.
Almmustuhtton: (2014)

Saturated heterocyclic chemistry

Saturated heterocyclic chemistry/
Almmustuhtton: (1974)

A highly regio- and stereoselective cascade annulation of enals and benzodi(enone)s catalyzed by N-heterocyclic carbenes
Dahkki: Fang, Xinqiang, et al.
Almmustuhtton: (2014)

N-heterocyclic carbene catalyzed homoenolate-addition reaction of enals and nitroalkenes : asymmetric synthesis of 5-carbon-synthon δ-nitroesters
Dahkki: Maji, Biswajit, et al.
Almmustuhtton: (2013)

β-Enamino Esters in Heterocyclic Synthesis: Synthesis of Pyrazolone and Pyridinone Derivatives
Dahkki: Abdellatif Mohamed Salaheldin, et al.
Almmustuhtton: (2010-06-01)

Aliphatic, alicyclic, and saturated heterocyclic chemistry

Oxidative N-heterocyclic carbene-catalyzed γ-carbon addition of enals to imines: mechanistic studies and access to antimicrobial compounds
Dahkki: Chi, Robin Yonggui, et al.
Almmustuhtton: (2015)

Diverse saturated heterocycles from a hydroacylation/conjugate addition cascade
Dahkki: Iwumene, N, et al.
Almmustuhtton: (2022)

Controlled β-protonation and [4+2] cycloaddition of enals and chalcones via N-heterocyclic carbene/acid catalysis : toward substrate independent reaction control
Dahkki: Fu, Zhenqian, et al.
Almmustuhtton: (2013)

Modern applications of transition metal catalysis in heterocycle synthesis
Dahkki: Willis, M
Almmustuhtton: (2009)

Oxidative γ-addition of enals to trifluoromethyl ketones : enantioselectivity control via Lewis acid/N-heterocyclic carbene cooperative catalysis
Dahkki: Mo, Junming, et al.
Almmustuhtton: (2013)

Synthesis of fused N-heterocycles utilizing the heterocyclic enamine protocol
Dahkki: Yong Liu, et al.
Almmustuhtton: (2003-05-01)

Synthesis and Characterization of New Heterocyclic Thioxanthone Derivatives
Almmustuhtton: (2013-09-01)

Synthesis of some Heterocyclic Compounds Derived from
Dahkki: Baghdad Science Journal
Almmustuhtton: (2013-09-01)

On the synthesis of heterocyclic dendrons
Dahkki: Enrique Díez-Barra, et al.
Almmustuhtton: (2002-02-01)

Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles
Dahkki: Dai, Xi-Jie, et al.
Almmustuhtton: (2020)

Homobimetallicruthenium-n-heterocyclic carbene complexes: synthesis, characterization, and catalytic applications/
Dahkki: 495863 Sauvage, Xavier, et al.

Synthesis and Regioselective Reaction of Some Unsymmetrical Heterocyclic Chalcone Derivatives and Spiro Heterocyclic Compounds as Antibacterial Agents
Dahkki: Maher A. El-Hashash, et al.
Almmustuhtton: (2015-12-01)

Palladium-catalysed enolate arylation in the synthesis of aromatic heterocycles and substituted heterocycles
Dahkki: Esteves, C
Almmustuhtton: (2017)

Dehydrogenative reagent-free annulation of alkenes with diols for the synthesis of saturated O-heterocycles
Dahkki: Chen-Yan Cai, et al.
Almmustuhtton: (2018-09-01)

β-Carbon activation of saturated carboxylic esters through N-heterocyclic carbene organocatalysis
Dahkki: Xu, Jianfeng, et al.
Almmustuhtton: (2013)

Synthesis and Characterization of Some N-Heterocyclic Carbohydrate Derivatives
Dahkki: M. A. Martins Alho, et al.
Almmustuhtton: (2000-03-01)

Reactions of nitrilimines with heterocyclic amines and enamines. Convenient methodology for synthesis and annulation of heterocycles
Dahkki: Ahmad S. Shawali, et al.
Almmustuhtton: (2007-02-01)

Synthesis of Quaternary Heterocyclic Salts
Dahkki: Angela J. Winstead, et al.
Almmustuhtton: (2013-11-01)

Azides in the Synthesis of Various Heterocycles
Dahkki: AbdElAziz A. Nayl, et al.
Almmustuhtton: (2022-06-01)

Design, Synthesis and Biological Activity Evaluation of β-Carboline Derivatives Containing Nitrogen Heterocycles
Dahkki: Guiyun Wu, et al.
Almmustuhtton: (2024-10-01)

Synthesis and Identification of Heterocyclic Compounds Derived from Ciprofloxacin
Dahkki: Shaima Ibraheem Chyad AL-khazraji
Almmustuhtton: (2018-06-01)

Synthesis and antibacterial activity of some heterocyclic derivatives of sulfanilamide
Dahkki: B.B. Subudhi, et al.
Almmustuhtton: (2012-12-01)

Synthesis and Discovery of Ligustrazine–Heterocycle Derivatives as Antitumor Agents
Dahkki: Shitang Ma, et al.
Almmustuhtton: (2022-07-01)

2-Oxiranecarbonitriles in the synthesis of linked quinono heterocyclic derivatives
Dahkki: Julija Volmajer, et al.
Almmustuhtton: (2003-09-01)