VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM
Voltammetric studies at a channel electrode irradiated with monochromatic visible light have been carried out to demonstrate that the photolysis of fac-Mo(CO)3{η3-[(Ph2PCH2CH 2)2PPh]}† in acetonitrile or dimethylformamide solution leads to the formation of the corresponding mer-isomer. No photofragm...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
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1995
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| _version_ | 1826302752434683904 |
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| author | Compton, R Eklund, J Hallik, A Kumbhat, S Bond, A Colton, R |
| author_facet | Compton, R Eklund, J Hallik, A Kumbhat, S Bond, A Colton, R |
| author_sort | Compton, R |
| collection | OXFORD |
| description | Voltammetric studies at a channel electrode irradiated with monochromatic visible light have been carried out to demonstrate that the photolysis of fac-Mo(CO)3{η3-[(Ph2PCH2CH 2)2PPh]}† in acetonitrile or dimethylformamide solution leads to the formation of the corresponding mer-isomer. No photofragmentation resulting in the loss of carbon monoxide or phosphine is observed on the voltammetric timescale. Kinetic parameters for the photo-isomerisation are reported. |
| first_indexed | 2024-03-07T05:52:18Z |
| format | Journal article |
| id | oxford-uuid:e94ef838-2ab0-4a76-8201-69c69dfc78fb |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:52:18Z |
| publishDate | 1995 |
| record_format | dspace |
| spelling | oxford-uuid:e94ef838-2ab0-4a76-8201-69c69dfc78fb2022-03-27T10:53:17ZVOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUMJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e94ef838-2ab0-4a76-8201-69c69dfc78fbEnglishSymplectic Elements at Oxford1995Compton, REklund, JHallik, AKumbhat, SBond, AColton, RVoltammetric studies at a channel electrode irradiated with monochromatic visible light have been carried out to demonstrate that the photolysis of fac-Mo(CO)3{η3-[(Ph2PCH2CH 2)2PPh]}† in acetonitrile or dimethylformamide solution leads to the formation of the corresponding mer-isomer. No photofragmentation resulting in the loss of carbon monoxide or phosphine is observed on the voltammetric timescale. Kinetic parameters for the photo-isomerisation are reported. |
| spellingShingle | Compton, R Eklund, J Hallik, A Kumbhat, S Bond, A Colton, R VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title | VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title_full | VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title_fullStr | VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title_full_unstemmed | VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title_short | VOLTAMMETRIC STUDY OF THE PHOTOLYSIS OF FAC-TRICARBONYL-ETA(3)-(BIS[2-(DIPHENYLPHOSPHINO)ETHYL]PHENYLPHOSPHINE)MOLYBDENUM |
| title_sort | voltammetric study of the photolysis of fac tricarbonyl eta 3 bis 2 diphenylphosphino ethyl phenylphosphine molybdenum |
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