New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible.
Cyclic voltammetry carried out at a wide range of supporting electrolyte concentrations and compositions can elucidate additional kinetic and mechanistic details of the electrochemical reduction of aryl halides. The cleavage of the C-Br bond is reversible, driven by H abstraction and the second elec...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2012
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| _version_ | 1826302831208955904 |
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| author | Wang, Y Barnes, E Compton, R |
| author_facet | Wang, Y Barnes, E Compton, R |
| author_sort | Wang, Y |
| collection | OXFORD |
| description | Cyclic voltammetry carried out at a wide range of supporting electrolyte concentrations and compositions can elucidate additional kinetic and mechanistic details of the electrochemical reduction of aryl halides. The cleavage of the C-Br bond is reversible, driven by H abstraction and the second electron transfer. This is a new chemical insight, as the cleavage of such bonds has usually been regarded as irreversible. |
| first_indexed | 2024-03-07T05:53:23Z |
| format | Journal article |
| id | oxford-uuid:e9aaf554-5fc8-4d23-8e7c-37114ce73b66 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:53:23Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:e9aaf554-5fc8-4d23-8e7c-37114ce73b662022-03-27T10:56:00ZNew chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e9aaf554-5fc8-4d23-8e7c-37114ce73b66EnglishSymplectic Elements at Oxford2012Wang, YBarnes, ECompton, RCyclic voltammetry carried out at a wide range of supporting electrolyte concentrations and compositions can elucidate additional kinetic and mechanistic details of the electrochemical reduction of aryl halides. The cleavage of the C-Br bond is reversible, driven by H abstraction and the second electron transfer. This is a new chemical insight, as the cleavage of such bonds has usually been regarded as irreversible. |
| spellingShingle | Wang, Y Barnes, E Compton, R New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title | New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title_full | New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title_fullStr | New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title_full_unstemmed | New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title_short | New chemical insights using weakly supported voltammetry: the reductive cleavage of Aryl-Br bonds is reversible. |
| title_sort | new chemical insights using weakly supported voltammetry the reductive cleavage of aryl br bonds is reversible |
| work_keys_str_mv | AT wangy newchemicalinsightsusingweaklysupportedvoltammetrythereductivecleavageofarylbrbondsisreversible AT barnese newchemicalinsightsusingweaklysupportedvoltammetrythereductivecleavageofarylbrbondsisreversible AT comptonr newchemicalinsightsusingweaklysupportedvoltammetrythereductivecleavageofarylbrbondsisreversible |