Li0.7NbS2: structural effects of increased alkali metal content
Crystals of lithium niobium disulfide [LiyNbS2; y = 0.70 (9)] have been prepared by separated reactants metathesis (SRM) at 1073 K. Single-crystal data collected at reduced temperature [150 (2) K] indicate that the compound is isostructural with Li0.63NbS2 [Salyer, Barker, Blake, Gregory and Wilson...
| Main Authors: | , , , , |
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| Format: | Journal article |
| Language: | English |
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2003
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| _version_ | 1797101553835835392 |
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| author | Salyer, P Barker, MG Gregory, D Jones, M Wilson, C |
| author_facet | Salyer, P Barker, MG Gregory, D Jones, M Wilson, C |
| author_sort | Salyer, P |
| collection | OXFORD |
| description | Crystals of lithium niobium disulfide [LiyNbS2; y = 0.70 (9)] have been prepared by separated reactants metathesis (SRM) at 1073 K. Single-crystal data collected at reduced temperature [150 (2) K] indicate that the compound is isostructural with Li0.63NbS2 [Salyer, Barker, Blake, Gregory and Wilson (2003). Acta Cryst. C59, i4-i6], crystallizing in the hexagonal space group P63/mmc (No. 194). Li 0.7NbS2 shows an expansion of both the a and c lattice parameters when compared with previously reported results on Li yNbS2 intercalation compounds with y < 0.70. This provides the first single-crystal structural evidence of unit cell expansion with increasing lithium content in LiyNbS2, where y > 0.5. κ 2003 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| first_indexed | 2024-03-07T05:53:29Z |
| format | Journal article |
| id | oxford-uuid:e9b52855-eb6a-498c-8306-4c957437cd6f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:53:29Z |
| publishDate | 2003 |
| record_format | dspace |
| spelling | oxford-uuid:e9b52855-eb6a-498c-8306-4c957437cd6f2022-03-27T10:56:11ZLi0.7NbS2: structural effects of increased alkali metal contentJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:e9b52855-eb6a-498c-8306-4c957437cd6fEnglishSymplectic Elements at Oxford2003Salyer, PBarker, MGGregory, DJones, MWilson, CCrystals of lithium niobium disulfide [LiyNbS2; y = 0.70 (9)] have been prepared by separated reactants metathesis (SRM) at 1073 K. Single-crystal data collected at reduced temperature [150 (2) K] indicate that the compound is isostructural with Li0.63NbS2 [Salyer, Barker, Blake, Gregory and Wilson (2003). Acta Cryst. C59, i4-i6], crystallizing in the hexagonal space group P63/mmc (No. 194). Li 0.7NbS2 shows an expansion of both the a and c lattice parameters when compared with previously reported results on Li yNbS2 intercalation compounds with y < 0.70. This provides the first single-crystal structural evidence of unit cell expansion with increasing lithium content in LiyNbS2, where y > 0.5. κ 2003 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| spellingShingle | Salyer, P Barker, MG Gregory, D Jones, M Wilson, C Li0.7NbS2: structural effects of increased alkali metal content |
| title | Li0.7NbS2: structural effects of increased alkali metal content |
| title_full | Li0.7NbS2: structural effects of increased alkali metal content |
| title_fullStr | Li0.7NbS2: structural effects of increased alkali metal content |
| title_full_unstemmed | Li0.7NbS2: structural effects of increased alkali metal content |
| title_short | Li0.7NbS2: structural effects of increased alkali metal content |
| title_sort | li0 7nbs2 structural effects of increased alkali metal content |
| work_keys_str_mv | AT salyerp li07nbs2structuraleffectsofincreasedalkalimetalcontent AT barkermg li07nbs2structuraleffectsofincreasedalkalimetalcontent AT gregoryd li07nbs2structuraleffectsofincreasedalkalimetalcontent AT jonesm li07nbs2structuraleffectsofincreasedalkalimetalcontent AT wilsonc li07nbs2structuraleffectsofincreasedalkalimetalcontent |