Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes
Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene...
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| Format: | Journal article |
| Language: | English |
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2001
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| _version_ | 1797101691816902656 |
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| author | Lai, S Drew, M Beer, P |
| author_facet | Lai, S Drew, M Beer, P |
| author_sort | Lai, S |
| collection | OXFORD |
| description | Novel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V. |
| first_indexed | 2024-03-07T05:55:25Z |
| format | Journal article |
| id | oxford-uuid:ea54b854-8aa7-4969-9655-8e0f8c02e66c |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T05:55:25Z |
| publishDate | 2001 |
| record_format | dspace |
| spelling | oxford-uuid:ea54b854-8aa7-4969-9655-8e0f8c02e66c2022-03-27T11:01:26ZMetal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ea54b854-8aa7-4969-9655-8e0f8c02e66cEnglishSymplectic Elements at Oxford2001Lai, SDrew, MBeer, PNovel redox-active polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes (10a-c), (11) and (12a-c) are synthesised by reaction of the respective ferrocenyl secondary amines, namely, N,N′-bis(ferrocenemethyl)-1,3-bis(aminomethyl)benzene (4), 1,1′-bis(benzylaminomethyl)ferrocene (8) and 1,1′-bis((ferrocenylmethyl)aminomethyl)ferrocene (9) with carbon disulfide, potassium hydroxide and transition metal (zinc, copper, nickel) acetate in high yields (52-82%) and characterised by spectroscopic and electrochemical techniques. The single-crystal X-ray structure of 10a shows that each zinc atom is in tetrahedral geometry, being bonded to two dithiocarbamate ligands with Zn-S distances 2.32(1)-2.44(1) Å. © 2001 Elsevier Science B.V. |
| spellingShingle | Lai, S Drew, M Beer, P Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title_full | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title_fullStr | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title_full_unstemmed | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title_short | Metal-directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| title_sort | metal directed assembly of polyferrocenyl transition metal dithiocarbamate macrocyclic molecular boxes |
| work_keys_str_mv | AT lais metaldirectedassemblyofpolyferrocenyltransitionmetaldithiocarbamatemacrocyclicmolecularboxes AT drewm metaldirectedassemblyofpolyferrocenyltransitionmetaldithiocarbamatemacrocyclicmolecularboxes AT beerp metaldirectedassemblyofpolyferrocenyltransitionmetaldithiocarbamatemacrocyclicmolecularboxes |