Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter
Acetylene (C 2 H 2 ) and ethane (C 2 H 6 ) are both produced in the stratosphere of Jupiter via photolysis of methane (CH 4 ). Despite this common source, the latitudinal distribution of the two species is radically different, with acetylene decreasing in abundance towards the pole, and ethane incre...
| Main Authors: | , , , , , , , , |
|---|---|
| Format: | Journal article |
| Published: |
Elsevier
2017
|
| _version_ | 1797101804938330112 |
|---|---|
| author | Melin, H Fletcher, L Donnelly, P Greathouse, T Lacy, J Orton, G Giles, R Sinclair, J Irwin, P |
| author_facet | Melin, H Fletcher, L Donnelly, P Greathouse, T Lacy, J Orton, G Giles, R Sinclair, J Irwin, P |
| author_sort | Melin, H |
| collection | OXFORD |
| description | Acetylene (C 2 H 2 ) and ethane (C 2 H 6 ) are both produced in the stratosphere of Jupiter via photolysis of methane (CH 4 ). Despite this common source, the latitudinal distribution of the two species is radically different, with acetylene decreasing in abundance towards the pole, and ethane increasing towards the pole. We present six years of NASA IRTF TEXES mid-infrared observations of the zonally-averaged emission of methane, acetylene and ethane. We confirm that the latitudinal distributions of ethane and acetylene are decoupled, and that this is a persistent feature over multiple years. The acetylene distribution falls off towards the pole, peaking at ~30°N with a volume mixing ratio (VMR) of ~0.8 parts per million (ppm) at 1 mbar and still falling off at ± 70° with a VMR of ~0.3 ppm. The acetylene distributions are asymmetric on average, but as we move from 2013 to 2017, the zonally-averaged abundance becomes more symmetric about the equator. We suggest that both the short term changes in acetylene and its latitudinal asymmetry is driven by changes to the vertical stratospheric mixing, potentially related to propagating wave phenomena. Unlike acetylene, ethane has a symmetric distribution about the equator that increases toward the pole, with a peak mole fraction of ~18 ppm at about ± 50° latitude, with a minimum at the equator of ~10 ppm at 1 mbar. The ethane distribution does not appear to respond to mid-latitude stratospheric mixing in the same way as acetylene, potentially as a result of the vertical gradient of ethane being much shallower than that of acetylene. The equator-to-pole distributions of acetylene and ethane are consistent with acetylene having a shorter lifetime than ethane that is not sensitive to longer advective timescales, but is augmented by short-term dynamics, such as vertical mixing. Conversely, the long lifetime of ethane allows it to be transported to higher latitudes faster than it can be chemically depleted. |
| first_indexed | 2024-03-07T05:57:05Z |
| format | Journal article |
| id | oxford-uuid:eae4ad55-999d-4322-b31c-dec76053ed7f |
| institution | University of Oxford |
| last_indexed | 2024-03-07T05:57:05Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:eae4ad55-999d-4322-b31c-dec76053ed7f2022-03-27T11:05:38ZAssessing the long-term variability of acetylene and ethane in the stratosphere of JupiterJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:eae4ad55-999d-4322-b31c-dec76053ed7fSymplectic Elements at OxfordElsevier2017Melin, HFletcher, LDonnelly, PGreathouse, TLacy, JOrton, GGiles, RSinclair, JIrwin, PAcetylene (C 2 H 2 ) and ethane (C 2 H 6 ) are both produced in the stratosphere of Jupiter via photolysis of methane (CH 4 ). Despite this common source, the latitudinal distribution of the two species is radically different, with acetylene decreasing in abundance towards the pole, and ethane increasing towards the pole. We present six years of NASA IRTF TEXES mid-infrared observations of the zonally-averaged emission of methane, acetylene and ethane. We confirm that the latitudinal distributions of ethane and acetylene are decoupled, and that this is a persistent feature over multiple years. The acetylene distribution falls off towards the pole, peaking at ~30°N with a volume mixing ratio (VMR) of ~0.8 parts per million (ppm) at 1 mbar and still falling off at ± 70° with a VMR of ~0.3 ppm. The acetylene distributions are asymmetric on average, but as we move from 2013 to 2017, the zonally-averaged abundance becomes more symmetric about the equator. We suggest that both the short term changes in acetylene and its latitudinal asymmetry is driven by changes to the vertical stratospheric mixing, potentially related to propagating wave phenomena. Unlike acetylene, ethane has a symmetric distribution about the equator that increases toward the pole, with a peak mole fraction of ~18 ppm at about ± 50° latitude, with a minimum at the equator of ~10 ppm at 1 mbar. The ethane distribution does not appear to respond to mid-latitude stratospheric mixing in the same way as acetylene, potentially as a result of the vertical gradient of ethane being much shallower than that of acetylene. The equator-to-pole distributions of acetylene and ethane are consistent with acetylene having a shorter lifetime than ethane that is not sensitive to longer advective timescales, but is augmented by short-term dynamics, such as vertical mixing. Conversely, the long lifetime of ethane allows it to be transported to higher latitudes faster than it can be chemically depleted. |
| spellingShingle | Melin, H Fletcher, L Donnelly, P Greathouse, T Lacy, J Orton, G Giles, R Sinclair, J Irwin, P Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title | Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title_full | Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title_fullStr | Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title_full_unstemmed | Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title_short | Assessing the long-term variability of acetylene and ethane in the stratosphere of Jupiter |
| title_sort | assessing the long term variability of acetylene and ethane in the stratosphere of jupiter |
| work_keys_str_mv | AT melinh assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT fletcherl assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT donnellyp assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT greathouset assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT lacyj assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT ortong assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT gilesr assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT sinclairj assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter AT irwinp assessingthelongtermvariabilityofacetyleneandethaneinthestratosphereofjupiter |