Structure and bonding in [Sb@In8Sb12]3− and [Sb@In8Sb12]5−
We report the characterization of the compound [K([2.2.2]crypt)]4 [In8 Sb13 ], which proves to contain a 1:1 mixture of [Sb@In8 Sb12 ]3- and [Sb@In8 Sb12 ]5- . The tri-anion displays perfect Th symmetry, the first completely inorganic molecule to do so, and contains eight equivalent In3+ centers in...
| Main Authors: | , , , , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
Wiley
2019
|