Bicyclo[10.2.1]pentadecenone derivatives by free radical macrocyclisation
The synthesis of intermediates for the preparation of stereoisomeric bicyclo[10.2.1]pentadec-13-en-3-ones is described. The preparation and the addition of 6-functionalised hexylcuprate reagents to bicyclic lactone 5 is discussed and a method described for the epimerisation of the so-formed trans-di...
| Hlavní autoři: | , , |
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| Médium: | Journal article |
| Jazyk: | English |
| Vydáno: |
1997
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