Experimental and Theoretical Characterization of the Magnetic Properties of CuF2(H2O)(2)(pyz) (pyz = pyrazine): A Two-Dimensional Quantum Magnet Arising from Supersuperexchange Interactions through Hydrogen Bonded Paths

Experimental and Theoretical Characterization of the Magnetic Properties of CuF2(H2O)(2)(pyz) (pyz = pyrazine): A Two-Dimensional Quantum Magnet Arising from Supersuperexchange Interactions through Hydrogen Bonded Paths

The structural, electronic, and magnetic properties of the new linear chain coordination polymer CuF 2(H 20) 2(pyz) (pyz = pyrazine) were determined by single crystal X-ray diffraction at various temperatures, SQUID magnetometry, pulsed-field magnetization, ESR, muon-spin relaxation (uSR), and elect...

Full description

Bibliographic Details
Main Authors:	Manson, J, Conner, M, Schlueter, J, McConnell, A, Southerland, H, Malfant, I, Lancaster, T, Blundell, S, Brooks, M, Pratt, F, Singleton, J, McDonald, R, Lee, C, Whangbo, M
Format:	Journal article
Language:	English
Published:	2008

Similar Items

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands.
by: Manson, J, et al.
Published: (2006)

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands.
by: Manson, J, et al.
Published: (2006)

Characterization of the antiferromagnetism in Ag(pyz)2(S2O8) (pyz = pyrazine) with a two-dimensional square lattice of Ag2+ ions.
by: Manson, J, et al.
Published: (2009)

Influence of HF2- geometry on magnetic interactions elucidated from polymorphs of the metal-organic framework [Ni(HF2)(pyz)2]PF6 (pyz = pyrazine).
by: Manson, J, et al.
Published: (2012)

Characterization of the crystal and magnetic structures of the mixed-anion coordination polymer Cu(HCO2)(NO3)(pyz) {pyz = Pyrazine} by X-ray diffraction, ac magnetic susceptibility, dc magnetization, muon-spin relaxation, and spin dimer analysis.
by: Manson, J, et al.
Published: (2007)

Structural, electronic, and magnetic properties of quasi-1D quantum magnets [Ni(HF2)(pyz)2]X (pyz = pyrazine; X = PF6(-), SbF6(-)) exhibiting Ni-FHF-Ni and Ni-pyz-Ni spin interactions.
by: Manson, J, et al.
Published: (2011)

Spin fluctuations and orbital ordering in quasi-one-dimensional alpha-Cu(dca)(2)(pyz) {dca = dicyanamide = N(CN)(2)(-); pyz = pyrazine}, a molecular analogue of KCuF3
by: Manson, J, et al.
Published: (2010)

Muon-spin relaxation studies of the low-dimensional molecular compounds Mn(dca)(2)(pyz) and Fe(NCS)(2)(pyz)(2)
by: Lancaster, T, et al.
Published: (2006)

Antiferromagnetism in a family of S = 1 square lattice coordination polymers NiX2(pyz)2 (X = Cl, Br, I, NCS; pyz = pyrazine)
by: Liu, J, et al.
Published: (2016)

[Cu(HF2)2(pyz)]n: A rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges
by: Manson, J, et al.
Published: (2011)

Magnetic order and enhanced exchange in the quasi-one-dimensional molecule-based antiferromagnet Cu(NO3)2(pyz)3
by: Huddart, B, et al.
Published: (2018)

Probing magnetic order and disorder in the one-dimensional molecular spin chains CuF2(pyz) and [Ln(hfac)3(boaDTDA)] n (Ln = Sm, La) using implanted muons
by: Lancaster, T, et al.
Published: (2019)

Electronic, magnetic and optical properties of reduced hybrid layered complex Ni(pyz)V4O10 (pyz=C4H4N2) by first-principles
by: Munir, J., et al.
Published: (2016)

Strong H...F hydrogen bonds as synthons in polymeric quantum magnets: structural, magnetic, and theoretical characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2.
by: Manson, J, et al.
Published: (2009)

Quantifying magnetic exchange in doubly-bridged Cu-X(2)-Cu (X = F, Cl, Br) chains enabled by solid state synthesis of CuF(2)(pyrazine).
by: Lapidus, S, et al.
Published: (2013)

Adsorption geometry and electronic structure of a charge-transfer-complex: TTF-PYZ2 on Ag(110)
by: Patrick Kretz, et al.
Published: (2021-01-01)

Antiferromagnetic ordering through a hydrogen-bonded network in the molecular solid CuF2(H2O)2(3-chloropyridine).
by: Lapidus, S, et al.
Published: (2013)

[Cu(HF2)2 (pyrazine)]n: a rectangular antiferromagnetic lattice with a spin exchange path made up of two different FHF- bridges.
by: Manson, J, et al.
Published: (2011)

[Cu(HF(2) )(2) (pyrazine)](n) : A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF(-) Bridges.
by: Manson, J, et al.
Published: (2011)

[Cu(HF(2))(2)(pyrazine)](n): A Rectangular Antiferromagnetic Lattice with a Spin Exchange Path Made Up of Two Different FHF(-) Bridges.
by: Manson, J, et al.
Published: (2011)

Magnetic order in the S=1/2 two-dimensional molecular antiferromagnet copper pyrazine perchlorate Cu(Pz)2(ClO4)2
by: Lancaster, T, et al.
Published: (2007)

Magnetic order in the S=1/2 two-dimensional molecular antiferromagnet copper pyrazine perchlorate Cu(Pz)(2)(ClO4)(2)
by: Lancaster, T, et al.
Published: (2007)

Importance of halogen···halogen contacts for the structural and magnetic properties of CuX2(pyrazine-N,N′-dioxide)(H2O)2 (X = Cl and Br).
by: Schlueter, J, et al.
Published: (2012)

Importance of halogen ··· halogen contacts for the structural and magnetic properties of CuX 2(pyrazine-N,N'-dioxide) (H 2O) 2 (X = Cl and Br)
by: Schlueter, J, et al.
Published: (2012)

Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation
by: Steele, A, et al.
Published: (2011)

Magnetic order in quasi-two-dimensional molecular magnets investigated with muon-spin relaxation
by: Steele, A, et al.
Published: (2011)

The magnetic ground state of two isostructual polymeric quantum magnets, [Cu(HF2)(pyrazine)SbF6 and [Co(HF2)(pyrazine)2]SbF6, investigated with neutron powder diffraction
by: Brambleby, J, et al.
Published: (2015)

Magnetic order in the quasi-one-dimensional spin-1/2 molecular chain compound copper pyrazine dinitrate
by: Lancaster, T, et al.
Published: (2006)

Magnetic order in the quasi-one-dimensional spin-1/2 molecular chain compound copper pyrazine dinitrate
by: Lancaster, T, et al.
Published: (2006)

Experimentally determining the exchange parameters of quasi-two-dimensional Heisenberg magnets
by: Goddard, P, et al.
Published: (2008)

Muon-fluorine entangled states in molecular magnets
by: Lancaster, T, et al.
Published: (2007)

Muon-fluorine entangled states in molecular magnets.
by: Lancaster, T, et al.
Published: (2007)

Structures and Properties of 4-phpy, pyz, and 4,4′-bpy Adducts of Lantern-Type Dirhodium Complexes with µ-Formamidinato and µ-Carboxylato Bridges
by: Makoto Handa, et al.
Published: (2021-03-01)

Mn(dca)2(o-phen) {dca = dicyanamide; O-phen = 1,10-phenanthroline}: Long-range magnetic order in a low-dimensional Mn-dca polymer
by: Manson, J, et al.
Published: (2013)

Mn(dca)(2)(o-phen) {dca = dicyanamide; o-phen=1,10-phenanthroline}: Long-range magnetic order in a low-dimensional Mn-dca polymer
by: Manson, J, et al.
Published: (2013)

Superconductivity and fluctuating magnetism in quasi-two-dimensional kappa-(BEDT-TTF)(2)Cu[N(CN)(2)]Br probed with implanted muons
by: Lancaster, T, et al.
Published: (2011)

Cu(HCO2)2(pym) (pym = pyrimidine): low-dimensional magnetic behavior and long-range ordering in a quantum-spin lattice.
by: Manson, J, et al.
Published: (2005)

Dimensionality selection in a molecule-based magnet.
by: Goddard, P, et al.
Published: (2012)

Spin dynamics and field-induced magnetic phase transition in the honeycomb Kitaev magnet alpha-Li2IrO3
by: Choi, S, et al.
Published: (2019)

Ag(nic)2 (nic = nicotinate): a spin-canted quasi-2D antiferromagnet composed of square-planar S = 1/2 Ag(II) ions.
by: Manson, J, et al.
Published: (2012)