cyclo{[(6-amino-6-deoxy-2,3 : 4,5-di-O-isopropylidene-D-galactonic acid)-( D-Phe)]2}

Determination of the crystal structure of the title compound [systematic name: 9,25-dibenzyl-4,4,15,15,20,20,31,31-octamethyl-3,5,14,16,19,21,30,32- octaoxa-8,11,24,27-tetraazapentacyclo[27.3.0.02,6.0 13,17.018,22]dotriacontane-7,10,23,26-tetrone], C 42H56N4O12, a cyclic tetramer, established the re...

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書目詳細資料
Main Authors: Bream, R, Watkin, D, Soengas, R, Fleet, G, Edwards, A, Hunter, S, Tranter, G
格式: Journal article
語言:English
出版: 2006
實物特徵
總結:Determination of the crystal structure of the title compound [systematic name: 9,25-dibenzyl-4,4,15,15,20,20,31,31-octamethyl-3,5,14,16,19,21,30,32- octaoxa-8,11,24,27-tetraazapentacyclo[27.3.0.02,6.0 13,17.018,22]dotriacontane-7,10,23,26-tetrone], C 42H56N4O12, a cyclic tetramer, established the relative stereochemistry of its ten stereogenic C atoms; an interesting saddle-like conformation is adopted. There are two molecules in the asymmetric unit. With the exception of the phenyl and isopropylidene groups, the molecules are related by a non-crystallographic twofold rotation axis. There are varying degrees of disorder in the isopropylidene groups. © 2006 International Union of Crystallography. All rights reserved.