(C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology
The title compound, poly[N,N,N′N′-tetramethylpropane-1,3-diaminium [aquatetraoxotri-μ3-sulfatodiuranate(VI)]], (C7H 20N2)[(UO2)2(SO4) 3(H2O)]n, contains two-dimensional [(UO 2)2(SO4)3(H20)] 2~ layers that are unprecedented in uranium chemistry. The layers in this compound are separated by C7H20N22+...
| Egile Nagusiak: | , , |
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| Formatua: | Journal article |
| Hizkuntza: | English |
| Argitaratua: |
2005
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| _version_ | 1826303275884871680 |
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| author | Norquist, A Doran, M O'Hare, D |
| author_facet | Norquist, A Doran, M O'Hare, D |
| author_sort | Norquist, A |
| collection | OXFORD |
| description | The title compound, poly[N,N,N′N′-tetramethylpropane-1,3-diaminium [aquatetraoxotri-μ3-sulfatodiuranate(VI)]], (C7H 20N2)[(UO2)2(SO4) 3(H2O)]n, contains two-dimensional [(UO 2)2(SO4)3(H20)] 2~ layers that are unprecedented in uranium chemistry. The layers in this compound are separated by C7H20N22+ cations, forming the basis of an extensive hydrogen-bonding network. An independent intralayer hydrogen-bonding network is also observed, involving water molecules bound directly to a uranium centre. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| first_indexed | 2024-03-07T06:00:11Z |
| format | Journal article |
| id | oxford-uuid:ebe9ccb5-68b2-441e-9af8-c859f6b24785 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:00:11Z |
| publishDate | 2005 |
| record_format | dspace |
| spelling | oxford-uuid:ebe9ccb5-68b2-441e-9af8-c859f6b247852022-03-27T11:13:30Z(C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topologyJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ebe9ccb5-68b2-441e-9af8-c859f6b24785EnglishSymplectic Elements at Oxford2005Norquist, ADoran, MO'Hare, DThe title compound, poly[N,N,N′N′-tetramethylpropane-1,3-diaminium [aquatetraoxotri-μ3-sulfatodiuranate(VI)]], (C7H 20N2)[(UO2)2(SO4) 3(H2O)]n, contains two-dimensional [(UO 2)2(SO4)3(H20)] 2~ layers that are unprecedented in uranium chemistry. The layers in this compound are separated by C7H20N22+ cations, forming the basis of an extensive hydrogen-bonding network. An independent intralayer hydrogen-bonding network is also observed, involving water molecules bound directly to a uranium centre. © 2005 International Union of Crystallography Printed in Great Britain - all rights reserved. |
| spellingShingle | Norquist, A Doran, M O'Hare, D (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title | (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title_full | (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title_fullStr | (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title_full_unstemmed | (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title_short | (C7H20N2)[(UO2)(2)(SO4)(3)(H2O)]: an organically templated uranium sulfate with a novel layer topology |
| title_sort | c7h20n2 uo2 2 so4 3 h2o an organically templated uranium sulfate with a novel layer topology |
| work_keys_str_mv | AT norquista c7h20n2uo22so43h2oanorganicallytemplateduraniumsulfatewithanovellayertopology AT doranm c7h20n2uo22so43h2oanorganicallytemplateduraniumsulfatewithanovellayertopology AT ohared c7h20n2uo22so43h2oanorganicallytemplateduraniumsulfatewithanovellayertopology |