Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes.
Microwave induced activation of electrochemical processes at microelectrodes (ca. 0.8 microm diameter) immersed in aqueous electrolyte media is shown to be driven by (i) continuous stable cavitation (giving rise to Faradaic current enhancements by up to three orders of magnitude) and (ii) transient...
| Main Authors: | , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2010
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| _version_ | 1797102219498094592 |
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| author | Rassaei, L Nebel, M Rees, N Compton, R Schuhmann, W Marken, F |
| author_facet | Rassaei, L Nebel, M Rees, N Compton, R Schuhmann, W Marken, F |
| author_sort | Rassaei, L |
| collection | OXFORD |
| description | Microwave induced activation of electrochemical processes at microelectrodes (ca. 0.8 microm diameter) immersed in aqueous electrolyte media is shown to be driven by (i) continuous stable cavitation (giving rise to Faradaic current enhancements by up to three orders of magnitude) and (ii) transient discharge cavitation on the micros timescale (giving rise to cathodic plasma current spikes and more violent surface erosion effects). |
| first_indexed | 2024-03-07T06:02:51Z |
| format | Journal article |
| id | oxford-uuid:ecd11200-4454-4ffd-8cda-69da0dab20f2 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:02:51Z |
| publishDate | 2010 |
| record_format | dspace |
| spelling | oxford-uuid:ecd11200-4454-4ffd-8cda-69da0dab20f22022-03-27T11:20:20ZDischarge cavitation during microwave electrochemistry at micrometre-sized electrodes.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ecd11200-4454-4ffd-8cda-69da0dab20f2EnglishSymplectic Elements at Oxford2010Rassaei, LNebel, MRees, NCompton, RSchuhmann, WMarken, FMicrowave induced activation of electrochemical processes at microelectrodes (ca. 0.8 microm diameter) immersed in aqueous electrolyte media is shown to be driven by (i) continuous stable cavitation (giving rise to Faradaic current enhancements by up to three orders of magnitude) and (ii) transient discharge cavitation on the micros timescale (giving rise to cathodic plasma current spikes and more violent surface erosion effects). |
| spellingShingle | Rassaei, L Nebel, M Rees, N Compton, R Schuhmann, W Marken, F Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title | Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title_full | Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title_fullStr | Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title_full_unstemmed | Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title_short | Discharge cavitation during microwave electrochemistry at micrometre-sized electrodes. |
| title_sort | discharge cavitation during microwave electrochemistry at micrometre sized electrodes |
| work_keys_str_mv | AT rassaeil dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes AT nebelm dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes AT reesn dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes AT comptonr dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes AT schuhmannw dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes AT markenf dischargecavitationduringmicrowaveelectrochemistryatmicrometresizedelectrodes |