Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation
We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...
Cur síos iomlán
Sonraí bibleagrafaíochta
| Príomhchruthaitheoirí: |
Robertson, J,
Hall, M,
Green, S |
|---|
| Formáid: | Journal article
|
|---|
| Teanga: | English |
|---|
| Foilsithe / Cruthaithe: |
2009
|
|---|