Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation
We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...
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| Những tác giả chính: |
Robertson, J,
Hall, M,
Green, S |
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| Định dạng: | Journal article
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| Ngôn ngữ: | English |
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| Được phát hành: |
2009
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