Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...

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Sonraí bibleagrafaíochta
Príomhchruthaitheoirí:	Robertson, J, Hall, M, Green, S
Formáid:	Journal article
Teanga:	English
Foilsithe / Cruthaithe:	2009

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