Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...

Бүрэн тодорхойлолт

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид:	Robertson, J, Hall, M, Green, S
Формат:	Journal article
Хэл сонгох:	English
Хэвлэсэн:	2009

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