Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

Stereospecific alpha-methallylation of hydroxyaldehydes by silatropic ene cyclisation

We describe the thermal rearrangement of aldehydes bearing an α-(allyl- or crotylsilyl)oxy substituent. The transformations are best described mechanistically as intramolecular silatropic ene reactions based on stereoselectivity, kinetic and computed transition state data. The overall process consti...

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Những tác giả chính:	Robertson, J, Hall, M, Green, S
Định dạng:	Journal article
Ngôn ngữ:	English
Được phát hành:	2009

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