Structural isomerism in the [(Ni@Sn9)In(Ni@Sn9)]5− Zintl ion†

Structural isomerism in the [(Ni@Sn9)In(Ni@Sn9)]5− Zintl ion†

A new Zintl cluster, [(Ni@Sn9)In(Ni@Sn9)]5−, has been isolated in two distinct isomeric forms, one where both Ni@Sn9 units are coordinated to the bridging In atom in an η3- mode, the other where one is η3- and the other η4-. Density functional theory indicates that the energetic separation between t...

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Bibliografiske detaljer
Main Authors:	Zhang, C, Morgan, H, Wang, Z, Liu, C, Sun, Z, McGrady, J
Format:	Journal article
Sprog:	English
Udgivet:	Royal Society of Chemistry 2019

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