Asymmetric electrophilic fluorocyclization with carbon nucleophiles.
Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chira...
| Main Authors: | , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2013
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| _version_ | 1797102323042877440 |
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| author | Wolstenhulme, JR Rosenqvist, J Lozano, O Ilupeju, J Wurz, N Engle, K Pidgeon, G Moore, P Sandford, G Gouverneur, V |
| author_facet | Wolstenhulme, JR Rosenqvist, J Lozano, O Ilupeju, J Wurz, N Engle, K Pidgeon, G Moore, P Sandford, G Gouverneur, V |
| author_sort | Wolstenhulme, JR |
| collection | OXFORD |
| description | Twist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| first_indexed | 2024-03-07T06:04:20Z |
| format | Journal article |
| id | oxford-uuid:ed50c753-279c-4d1d-b180-4eb98188855d |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:04:20Z |
| publishDate | 2013 |
| record_format | dspace |
| spelling | oxford-uuid:ed50c753-279c-4d1d-b180-4eb98188855d2022-03-27T11:24:07ZAsymmetric electrophilic fluorocyclization with carbon nucleophiles.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ed50c753-279c-4d1d-b180-4eb98188855dEnglishSymplectic Elements at Oxford2013Wolstenhulme, JRRosenqvist, JLozano, OIlupeju, JWurz, NEngle, KPidgeon, GMoore, PSandford, GGouverneur, VTwist of 'F'ate: Various helical-shaped fluorinated tetracyclic molecules were prepared by fluorocarbocyclization of prochiral alkenes. The development of a new class of chiral Selectfluor (1) proved instrumental in developing an asymmetric variant of this transformation. These novel chiral N-F reagents are readily accessible by fluorine transfer from shelf-stable N-fluoropyridinium salts. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
| spellingShingle | Wolstenhulme, JR Rosenqvist, J Lozano, O Ilupeju, J Wurz, N Engle, K Pidgeon, G Moore, P Sandford, G Gouverneur, V Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title | Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title_full | Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title_fullStr | Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title_full_unstemmed | Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title_short | Asymmetric electrophilic fluorocyclization with carbon nucleophiles. |
| title_sort | asymmetric electrophilic fluorocyclization with carbon nucleophiles |
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