Lithiation-induced migrations from nitrogen to carbon in terminal aziridines.
(Chemical Equation Presented) Benefiting from deprotection: Lithium 2,2,6,6-tetramethylpiperidide induces N-Boc or N-phosphonate terminal aziridines to undergo regio- and stereoselective N-to-C migration of the protecting group, giving synthetically valuable trans-aziridinylesters and trans- aziridi...
| Main Authors: | , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2007
|
| _version_ | 1797102426950467584 |
|---|---|
| author | Hodgson, D Humphreys, P Xu, Z Ward, J |
| author_facet | Hodgson, D Humphreys, P Xu, Z Ward, J |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | (Chemical Equation Presented) Benefiting from deprotection: Lithium 2,2,6,6-tetramethylpiperidide induces N-Boc or N-phosphonate terminal aziridines to undergo regio- and stereoselective N-to-C migration of the protecting group, giving synthetically valuable trans-aziridinylesters and trans- aziridinylphosphonates. © 2007 Wiley-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T06:05:52Z |
| format | Journal article |
| id | oxford-uuid:edd248b0-40cd-4562-9e34-824497cba474 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:05:52Z |
| publishDate | 2007 |
| record_format | dspace |
| spelling | oxford-uuid:edd248b0-40cd-4562-9e34-824497cba4742022-03-27T11:27:56ZLithiation-induced migrations from nitrogen to carbon in terminal aziridines.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:edd248b0-40cd-4562-9e34-824497cba474EnglishSymplectic Elements at Oxford2007Hodgson, DHumphreys, PXu, ZWard, J(Chemical Equation Presented) Benefiting from deprotection: Lithium 2,2,6,6-tetramethylpiperidide induces N-Boc or N-phosphonate terminal aziridines to undergo regio- and stereoselective N-to-C migration of the protecting group, giving synthetically valuable trans-aziridinylesters and trans- aziridinylphosphonates. © 2007 Wiley-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Hodgson, D Humphreys, P Xu, Z Ward, J Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title | Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title_full | Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title_fullStr | Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title_full_unstemmed | Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title_short | Lithiation-induced migrations from nitrogen to carbon in terminal aziridines. |
| title_sort | lithiation induced migrations from nitrogen to carbon in terminal aziridines |
| work_keys_str_mv | AT hodgsond lithiationinducedmigrationsfromnitrogentocarboninterminalaziridines AT humphreysp lithiationinducedmigrationsfromnitrogentocarboninterminalaziridines AT xuz lithiationinducedmigrationsfromnitrogentocarboninterminalaziridines AT wardj lithiationinducedmigrationsfromnitrogentocarboninterminalaziridines |