Dimensionality selection in a molecule-based magnet.
Gaining control of the building blocks of magnetic materials and thereby achieving particular characteristics will make possible the design and growth of bespoke magnetic devices. While progress in the synthesis of molecular materials, and especially coordination polymers, represents a significant s...
| Main Authors: | , , , , , , , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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| _version_ | 1797102576673488896 |
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| author | Goddard, P Manson, J Singleton, J Franke, I Lancaster, T Steele, A Blundell, S Baines, C Pratt, F McDonald, R Ayala-Valenzuela, O Corbey, J Southerland, H Sengupta, P Schlueter, J |
| author_facet | Goddard, P Manson, J Singleton, J Franke, I Lancaster, T Steele, A Blundell, S Baines, C Pratt, F McDonald, R Ayala-Valenzuela, O Corbey, J Southerland, H Sengupta, P Schlueter, J |
| author_sort | Goddard, P |
| collection | OXFORD |
| description | Gaining control of the building blocks of magnetic materials and thereby achieving particular characteristics will make possible the design and growth of bespoke magnetic devices. While progress in the synthesis of molecular materials, and especially coordination polymers, represents a significant step towards this goal, the ability to tune the magnetic interactions within a particular framework remains in its infancy. Here we demonstrate a chemical method which achieves dimensionality selection via preferential inhibition of the magnetic exchange in an S=1/2 antiferromagnet along one crystal direction, switching the system from being quasi-two- to quasi-one-dimensional while effectively maintaining the nearest-neighbor coupling strength. |
| first_indexed | 2024-03-07T06:07:53Z |
| format | Journal article |
| id | oxford-uuid:ee767272-d5c7-42a9-9597-e6db624f07c0 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:07:53Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:ee767272-d5c7-42a9-9597-e6db624f07c02022-03-27T11:32:57ZDimensionality selection in a molecule-based magnet.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ee767272-d5c7-42a9-9597-e6db624f07c0EnglishSymplectic Elements at Oxford2012Goddard, PManson, JSingleton, JFranke, ILancaster, TSteele, ABlundell, SBaines, CPratt, FMcDonald, RAyala-Valenzuela, OCorbey, JSoutherland, HSengupta, PSchlueter, JGaining control of the building blocks of magnetic materials and thereby achieving particular characteristics will make possible the design and growth of bespoke magnetic devices. While progress in the synthesis of molecular materials, and especially coordination polymers, represents a significant step towards this goal, the ability to tune the magnetic interactions within a particular framework remains in its infancy. Here we demonstrate a chemical method which achieves dimensionality selection via preferential inhibition of the magnetic exchange in an S=1/2 antiferromagnet along one crystal direction, switching the system from being quasi-two- to quasi-one-dimensional while effectively maintaining the nearest-neighbor coupling strength. |
| spellingShingle | Goddard, P Manson, J Singleton, J Franke, I Lancaster, T Steele, A Blundell, S Baines, C Pratt, F McDonald, R Ayala-Valenzuela, O Corbey, J Southerland, H Sengupta, P Schlueter, J Dimensionality selection in a molecule-based magnet. |
| title | Dimensionality selection in a molecule-based magnet. |
| title_full | Dimensionality selection in a molecule-based magnet. |
| title_fullStr | Dimensionality selection in a molecule-based magnet. |
| title_full_unstemmed | Dimensionality selection in a molecule-based magnet. |
| title_short | Dimensionality selection in a molecule-based magnet. |
| title_sort | dimensionality selection in a molecule based magnet |
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