Enantioselectivity in the boron aldol reactions of methyl ketones.

DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.

Bibliografiska uppgifter
Huvudupphovsmän: Goodman, J, Paton, R
Materialtyp: Journal article
Språk:English
Publicerad: Royal Society of Chemistry 2007
Beskrivning
Sammanfattning:DFT computed transition states quantitatively explain the surprising stereochemical outcome of unsubstituted enolborinates in diastereoselective and enantioselective boron aldol reactions.