Synthesis of polyyne rotaxanes.
Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. The crystal structure of the C12 rotaxane has been determined. In the rhenium(I) carbonyl complex of this rotaxane, with Re(CO)(3)Cl coordina...
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| Hlavní autoři: |
Movsisyan, L,
Kondratuk, D,
Franz, M,
Thompson, A,
Tykwinski, R,
Anderson, H |
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| Médium: | Journal article
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| Jazyk: | English |
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| Vydáno: |
2012
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