Synthesis of polyyne rotaxanes.

Active-metal templating has been used to synthesize rotaxanes consisting of a phenanthroline-based macrocycle threaded around a C8, C12, or C20 polyyne chain. The crystal structure of the C12 rotaxane has been determined. In the rhenium(I) carbonyl complex of this rotaxane, with Re(CO)(3)Cl coordina...

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Những tác giả chính: Movsisyan, L, Kondratuk, D, Franz, M, Thompson, A, Tykwinski, R, Anderson, H
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2012