Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks.
I want to ride my azacycle: The title reaction of enynamides affords a wide diversity of azacycles. The reactions are high-yielding, highly stereoselective, and proceed rapidly under mild reaction conditions. Equivalent transformations using enynhydrazides offer new routes to pyrazole and indazole s...
Main Authors: | , , , , |
---|---|
Format: | Journal article |
Language: | English |
Published: |
2013
|
_version_ | 1797102716794699776 |
---|---|
author | Walker, P Campbell, C Suleman, A Carr, G Anderson, E |
author_facet | Walker, P Campbell, C Suleman, A Carr, G Anderson, E |
author_sort | Walker, P |
collection | OXFORD |
description | I want to ride my azacycle: The title reaction of enynamides affords a wide diversity of azacycles. The reactions are high-yielding, highly stereoselective, and proceed rapidly under mild reaction conditions. Equivalent transformations using enynhydrazides offer new routes to pyrazole and indazole scaffolds. Boc=tert-butoxycarbonyl, EWG=electron-withdrawing group, Ns=4-nitrobenzenesulfonyl, Ts=4-toluenesulfonyl. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
first_indexed | 2024-03-07T06:09:44Z |
format | Journal article |
id | oxford-uuid:ef0f5b2e-1109-4e42-85e5-2f060c9b5f45 |
institution | University of Oxford |
language | English |
last_indexed | 2024-03-07T06:09:44Z |
publishDate | 2013 |
record_format | dspace |
spelling | oxford-uuid:ef0f5b2e-1109-4e42-85e5-2f060c9b5f452022-03-27T11:37:36ZPalladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:ef0f5b2e-1109-4e42-85e5-2f060c9b5f45EnglishSymplectic Elements at Oxford2013Walker, PCampbell, CSuleman, ACarr, GAnderson, EI want to ride my azacycle: The title reaction of enynamides affords a wide diversity of azacycles. The reactions are high-yielding, highly stereoselective, and proceed rapidly under mild reaction conditions. Equivalent transformations using enynhydrazides offer new routes to pyrazole and indazole scaffolds. Boc=tert-butoxycarbonyl, EWG=electron-withdrawing group, Ns=4-nitrobenzenesulfonyl, Ts=4-toluenesulfonyl. Copyright © 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim. |
spellingShingle | Walker, P Campbell, C Suleman, A Carr, G Anderson, E Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title | Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title_full | Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title_fullStr | Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title_full_unstemmed | Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title_short | Palladium- and ruthenium-catalyzed cycloisomerization of enynamides and enynhydrazides: a rapid approach to diverse azacyclic frameworks. |
title_sort | palladium and ruthenium catalyzed cycloisomerization of enynamides and enynhydrazides a rapid approach to diverse azacyclic frameworks |
work_keys_str_mv | AT walkerp palladiumandrutheniumcatalyzedcycloisomerizationofenynamidesandenynhydrazidesarapidapproachtodiverseazacyclicframeworks AT campbellc palladiumandrutheniumcatalyzedcycloisomerizationofenynamidesandenynhydrazidesarapidapproachtodiverseazacyclicframeworks AT sulemana palladiumandrutheniumcatalyzedcycloisomerizationofenynamidesandenynhydrazidesarapidapproachtodiverseazacyclicframeworks AT carrg palladiumandrutheniumcatalyzedcycloisomerizationofenynamidesandenynhydrazidesarapidapproachtodiverseazacyclicframeworks AT andersone palladiumandrutheniumcatalyzedcycloisomerizationofenynamidesandenynhydrazidesarapidapproachtodiverseazacyclicframeworks |