Structure and magnetism of the topotactically reduced oxychloride Sr4Mn3O(6.5)Cl2.
Reaction of the n = 3 Ruddlesden-Popper oxychloride Sr(4)Mn(3)O(7.5)Cl(2) with calcium hydride yields the topotactically reduced phase Sr(4)Mn(3)O(6.5)Cl(2). The deintercalation of oxide ions from the central MnO(1.5) layer of the starting phase is accompanied by a rearrangement of the anion lattice...
المؤلفون الرئيسيون: | Romero, F, Hayward, M |
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التنسيق: | Journal article |
اللغة: | English |
منشور في: |
2012
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مواد مشابهة
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Topotactic reduction of transition metal oxychlorides: A contrast to oxide chemistry
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