Structure and magnetism of the topotactically reduced oxychloride Sr4Mn3O(6.5)Cl2.
Reaction of the n = 3 Ruddlesden-Popper oxychloride Sr(4)Mn(3)O(7.5)Cl(2) with calcium hydride yields the topotactically reduced phase Sr(4)Mn(3)O(6.5)Cl(2). The deintercalation of oxide ions from the central MnO(1.5) layer of the starting phase is accompanied by a rearrangement of the anion lattice...
| Main Authors: | , |
|---|---|
| 格式: | Journal article |
| 語言: | English |
| 出版: |
2012
|