The synthesis of melohenine B and a related natural product

A concise synthesis of melohenine B and O-ethyl-14-epimelohenine B, from eburnamonine, was achieved via a biomimetic diastereoselective singlet oxygen-mediated oxidative cleavage of the indole C2–C7 bond. These studies enabled the assignment of the absolute configuration of the natural products. In...

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Autori principali: Lancefield, CS, Zhou, L, Lébl, T, Slawin, AMZ, Westwood, NJ
Natura: Journal article
Lingua:English
Pubblicazione: American Chemical Society 2012