Synthesis of amino-sugars using the directed dihydroxylation reaction
The synthesis of protected forms of two amino-sugars, talosamine 1 and allosamine 2, is described; the syn, syn stereochemistry at C-2, C-3 and C-4 was controlled by the use of a hydrogen-bonding directed dihydroxylation reaction using stoichiometric and catalytic OsO4; proof of the relative stereoc...
| Hoofdauteurs: | , , |
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| Formaat: | Journal article |
| Taal: | English |
| Gepubliceerd in: |
1999
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| _version_ | 1826304157370286080 |
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| author | Donohoe, T Blades, K Helliwell, M |
| author_facet | Donohoe, T Blades, K Helliwell, M |
| author_sort | Donohoe, T |
| collection | OXFORD |
| description | The synthesis of protected forms of two amino-sugars, talosamine 1 and allosamine 2, is described; the syn, syn stereochemistry at C-2, C-3 and C-4 was controlled by the use of a hydrogen-bonding directed dihydroxylation reaction using stoichiometric and catalytic OsO4; proof of the relative stereochemistry of the allosamine series was obtained through an X-ray crystal structure of a protected derivative. |
| first_indexed | 2024-03-07T06:13:32Z |
| format | Journal article |
| id | oxford-uuid:f056e75f-2ff8-463d-b36e-abc0513870ce |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:13:32Z |
| publishDate | 1999 |
| record_format | dspace |
| spelling | oxford-uuid:f056e75f-2ff8-463d-b36e-abc0513870ce2022-03-27T11:47:07ZSynthesis of amino-sugars using the directed dihydroxylation reactionJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f056e75f-2ff8-463d-b36e-abc0513870ceEnglishSymplectic Elements at Oxford1999Donohoe, TBlades, KHelliwell, MThe synthesis of protected forms of two amino-sugars, talosamine 1 and allosamine 2, is described; the syn, syn stereochemistry at C-2, C-3 and C-4 was controlled by the use of a hydrogen-bonding directed dihydroxylation reaction using stoichiometric and catalytic OsO4; proof of the relative stereochemistry of the allosamine series was obtained through an X-ray crystal structure of a protected derivative. |
| spellingShingle | Donohoe, T Blades, K Helliwell, M Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title | Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title_full | Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title_fullStr | Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title_full_unstemmed | Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title_short | Synthesis of amino-sugars using the directed dihydroxylation reaction |
| title_sort | synthesis of amino sugars using the directed dihydroxylation reaction |
| work_keys_str_mv | AT donohoet synthesisofaminosugarsusingthedirecteddihydroxylationreaction AT bladesk synthesisofaminosugarsusingthedirecteddihydroxylationreaction AT helliwellm synthesisofaminosugarsusingthedirecteddihydroxylationreaction |