Substituted epoxides by lithiation of terminal epoxides.
Diamine-ligand-assisted direct hydrogen-lithium exchange allows the generation of nonstabilized (H-substituted) oxiranyllithium species and their subsequent trapping by Bu(3)SnCl and carbonyl-based electrophiles. This reaction provides a new concise route to alpha,beta-epoxystannanes and substituted...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2004
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| _version_ | 1797103045441486848 |
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| author | Hodgson, D Reynolds, N Coote, S |
| author_facet | Hodgson, D Reynolds, N Coote, S |
| author_sort | Hodgson, D |
| collection | OXFORD |
| description | Diamine-ligand-assisted direct hydrogen-lithium exchange allows the generation of nonstabilized (H-substituted) oxiranyllithium species and their subsequent trapping by Bu(3)SnCl and carbonyl-based electrophiles. This reaction provides a new concise route to alpha,beta-epoxystannanes and substituted epoxides. |
| first_indexed | 2024-03-07T06:14:28Z |
| format | Journal article |
| id | oxford-uuid:f09d53d9-df3e-4934-a49d-003f1d5c8a57 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:14:28Z |
| publishDate | 2004 |
| record_format | dspace |
| spelling | oxford-uuid:f09d53d9-df3e-4934-a49d-003f1d5c8a572022-03-27T11:49:30ZSubstituted epoxides by lithiation of terminal epoxides.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f09d53d9-df3e-4934-a49d-003f1d5c8a57EnglishSymplectic Elements at Oxford2004Hodgson, DReynolds, NCoote, SDiamine-ligand-assisted direct hydrogen-lithium exchange allows the generation of nonstabilized (H-substituted) oxiranyllithium species and their subsequent trapping by Bu(3)SnCl and carbonyl-based electrophiles. This reaction provides a new concise route to alpha,beta-epoxystannanes and substituted epoxides. |
| spellingShingle | Hodgson, D Reynolds, N Coote, S Substituted epoxides by lithiation of terminal epoxides. |
| title | Substituted epoxides by lithiation of terminal epoxides. |
| title_full | Substituted epoxides by lithiation of terminal epoxides. |
| title_fullStr | Substituted epoxides by lithiation of terminal epoxides. |
| title_full_unstemmed | Substituted epoxides by lithiation of terminal epoxides. |
| title_short | Substituted epoxides by lithiation of terminal epoxides. |
| title_sort | substituted epoxides by lithiation of terminal epoxides |
| work_keys_str_mv | AT hodgsond substitutedepoxidesbylithiationofterminalepoxides AT reynoldsn substitutedepoxidesbylithiationofterminalepoxides AT cootes substitutedepoxidesbylithiationofterminalepoxides |