Substituted epoxides by lithiation of terminal epoxides.
Diamine-ligand-assisted direct hydrogen-lithium exchange allows the generation of nonstabilized (H-substituted) oxiranyllithium species and their subsequent trapping by Bu(3)SnCl and carbonyl-based electrophiles. This reaction provides a new concise route to alpha,beta-epoxystannanes and substituted...
Κύριοι συγγραφείς: | Hodgson, D, Reynolds, N, Coote, S |
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Μορφή: | Journal article |
Γλώσσα: | English |
Έκδοση: |
2004
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Παρόμοια τεκμήρια
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Recent developments in the chemistry of lithiated epoxides
ανά: Hodgson, D, κ.ά.
Έκδοση: (2002) -
Deprotonation-electrophile trapping of terminal epoxides.
ανά: Hodgson, D, κ.ά.
Έκδοση: (2005) -
Expanding the utility of lithiated epoxides and aziridines in synthesis
ανά: Hodgson, D, κ.ά.
Έκδοση: (2006) -
Alkenes from β-lithiooxyphosphonium ylides generated by trapping α-lithiated terminal epoxides with triphenylphosphine.
ανά: Hodgson, D, κ.ά.
Έκδοση: (2012) -
syn-β-Hydroxyallylic silanes from terminal epoxide α-lithiation-silylation and alkenylation: application to the tetrahydrofuran portion of the lytophilippines.
ανά: Hodgson, D, κ.ά.
Έκδοση: (2012)