Substituted epoxides by lithiation of terminal epoxides.

Diamine-ligand-assisted direct hydrogen-lithium exchange allows the generation of nonstabilized (H-substituted) oxiranyllithium species and their subsequent trapping by Bu(3)SnCl and carbonyl-based electrophiles. This reaction provides a new concise route to alpha,beta-epoxystannanes and substituted...

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Những tác giả chính: Hodgson, D, Reynolds, N, Coote, S
Định dạng: Journal article
Ngôn ngữ:English
Được phát hành: 2004