Examining the edges of multi-layer graphene sheets

Multi-layer graphene (MLG) sheets were produced from highly ordered pyrolytic graphite by mechanical exfoliation. We use aberration-corrected, low-voltage, high-resolution transmission electron microscopy to study the atomic structure at the edges of the sheets. In general, we find two different typ...

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Main Authors: Warner, J, Schäffel, F, Rümmeli, M, Büchner, B
Format: Journal article
Language:English
Published: 2009
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author Warner, J
Schäffel, F
Rümmeli, M
Büchner, B
author_facet Warner, J
Schäffel, F
Rümmeli, M
Büchner, B
author_sort Warner, J
collection OXFORD
description Multi-layer graphene (MLG) sheets were produced from highly ordered pyrolytic graphite by mechanical exfoliation. We use aberration-corrected, low-voltage, high-resolution transmission electron microscopy to study the atomic structure at the edges of the sheets. In general, we find two different types of edges of MLG sheets are produced, either parallel to a zigzag direction or an arm-chair direction. A MLG sheet with edges parallel to the zigzag direction was observed to have small random corrugations and was relatively straight. We observed edges parallel to the arm-chair direction with highly corrugated atomic structure and terracing. We show that the corrugations are due to sawtooth oscillations in the atomic structure with zigzag edge terminations along the general arm-chair direction. © 2009 American Chemical Society.
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spelling oxford-uuid:f1e79c5f-1c05-4fa8-a0f1-1366af95e6182022-03-27T11:59:33ZExamining the edges of multi-layer graphene sheetsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f1e79c5f-1c05-4fa8-a0f1-1366af95e618EnglishSymplectic Elements at Oxford2009Warner, JSchäffel, FRümmeli, MBüchner, BMulti-layer graphene (MLG) sheets were produced from highly ordered pyrolytic graphite by mechanical exfoliation. We use aberration-corrected, low-voltage, high-resolution transmission electron microscopy to study the atomic structure at the edges of the sheets. In general, we find two different types of edges of MLG sheets are produced, either parallel to a zigzag direction or an arm-chair direction. A MLG sheet with edges parallel to the zigzag direction was observed to have small random corrugations and was relatively straight. We observed edges parallel to the arm-chair direction with highly corrugated atomic structure and terracing. We show that the corrugations are due to sawtooth oscillations in the atomic structure with zigzag edge terminations along the general arm-chair direction. © 2009 American Chemical Society.
spellingShingle Warner, J
Schäffel, F
Rümmeli, M
Büchner, B
Examining the edges of multi-layer graphene sheets
title Examining the edges of multi-layer graphene sheets
title_full Examining the edges of multi-layer graphene sheets
title_fullStr Examining the edges of multi-layer graphene sheets
title_full_unstemmed Examining the edges of multi-layer graphene sheets
title_short Examining the edges of multi-layer graphene sheets
title_sort examining the edges of multi layer graphene sheets
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