Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides
Dihydrogen loss from the 14-electron Rh(III) bis-phosphine dihydride [Rh(PiBu3)2H2][BArF4] forms a complex tentatively identified as [Rh(PiBu 3)2(L2)][BArF4] (L 2 = solvent or agostic interactions), which reacts with dichloro ethane or fluorobenzene to form [Rh(PiBu3) 2(ClCH2CH2Cl)][BArF4] and [Rh(P...
| Main Authors: | , , |
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| Format: | Journal article |
| Language: | English |
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2008
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| _version_ | 1797103571507871744 |
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| author | Douglas, T Chaplin, AB Weller, A |
| author_facet | Douglas, T Chaplin, AB Weller, A |
| author_sort | Douglas, T |
| collection | OXFORD |
| description | Dihydrogen loss from the 14-electron Rh(III) bis-phosphine dihydride [Rh(PiBu3)2H2][BArF4] forms a complex tentatively identified as [Rh(PiBu 3)2(L2)][BArF4] (L 2 = solvent or agostic interactions), which reacts with dichloro ethane or fluorobenzene to form [Rh(PiBu3) 2(ClCH2CH2Cl)][BArF4] and [Rh(PiBu3)2(η6-C 6H5F)][BArF4], respectively. [Rh(PiBu3)2(L)2[-[BAr F4] or its adducts undergo oxidative addition of aryl halides (C6H5X; X = Cl, Br) at room temperature to give the dimeric species [Rh(PiBu3)2(C 6H5)(μ-X)]2. © 2008 American Chemical Society. |
| first_indexed | 2024-03-07T06:22:00Z |
| format | Journal article |
| id | oxford-uuid:f3036882-8aa3-4c67-a260-c95dc3d39318 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:22:00Z |
| publishDate | 2008 |
| record_format | dspace |
| spelling | oxford-uuid:f3036882-8aa3-4c67-a260-c95dc3d393182022-03-27T12:08:41ZDihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chloridesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f3036882-8aa3-4c67-a260-c95dc3d39318EnglishSymplectic Elements at Oxford2008Douglas, TChaplin, ABWeller, ADihydrogen loss from the 14-electron Rh(III) bis-phosphine dihydride [Rh(PiBu3)2H2][BArF4] forms a complex tentatively identified as [Rh(PiBu 3)2(L2)][BArF4] (L 2 = solvent or agostic interactions), which reacts with dichloro ethane or fluorobenzene to form [Rh(PiBu3) 2(ClCH2CH2Cl)][BArF4] and [Rh(PiBu3)2(η6-C 6H5F)][BArF4], respectively. [Rh(PiBu3)2(L)2[-[BAr F4] or its adducts undergo oxidative addition of aryl halides (C6H5X; X = Cl, Br) at room temperature to give the dimeric species [Rh(PiBu3)2(C 6H5)(μ-X)]2. © 2008 American Chemical Society. |
| spellingShingle | Douglas, T Chaplin, AB Weller, A Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title | Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title_full | Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title_fullStr | Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title_full_unstemmed | Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title_short | Dihydrogen loss from a 14-electron rhodium(III) bis-phosphine dihydride to give a rhodium(I) complex that undergoes oxidative addition with aryl chlorides |
| title_sort | dihydrogen loss from a 14 electron rhodium iii bis phosphine dihydride to give a rhodium i complex that undergoes oxidative addition with aryl chlorides |
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