Magnetic properties of the 6H Perovskite Ba3Fe2TeO9
<p>A polycrystalline sample of Ba<sub>3</sub>Fe<sub>2</sub>TeO<sub>9</sub> having the 6H perovskite structure has been prepared in a solid-state reaction and studied by a combination of electron microscopy, Mössbauer spectroscopy, magnetometry, X-ray diffra...
| Main Authors: | , , , , |
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| Format: | Journal article |
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Elsevier
2017
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| _version_ | 1826304735970328576 |
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| author | Tang, Y Sena, RP Avdeev, M Battle, PD Hunter, EC |
| author_facet | Tang, Y Sena, RP Avdeev, M Battle, PD Hunter, EC |
| author_sort | Tang, Y |
| collection | OXFORD |
| description | <p>A polycrystalline sample of Ba<sub>3</sub>Fe<sub>2</sub>TeO<sub>9</sub> having the 6H perovskite structure has been prepared in a solid-state reaction and studied by a combination of electron microscopy, Mössbauer spectroscopy, magnetometry, X-ray diffraction and neutron diffraction. Partial ordering of Fe<sup>3+</sup> and Te<sup>6+</sup> cations occurs over the six-coordinate sites; the corner-sharing octahedra are predominantly occupied by the former and the face-sharing octahedra by a 1:1 mixture of the two. On cooling through the temperature range 18 < T/K < 295 an increasing number of spins join an antiferromagnetic backbone running through the structure while the remainder show complex relaxation effects. At 3 K an antiferromagnetic phase and a spin glass coexist.</p> |
| first_indexed | 2024-03-07T06:22:18Z |
| format | Journal article |
| id | oxford-uuid:f31bf4c1-e9db-47f6-8bb1-3e2353e715a0 |
| institution | University of Oxford |
| last_indexed | 2024-03-07T06:22:18Z |
| publishDate | 2017 |
| publisher | Elsevier |
| record_format | dspace |
| spelling | oxford-uuid:f31bf4c1-e9db-47f6-8bb1-3e2353e715a02022-03-27T12:09:27ZMagnetic properties of the 6H Perovskite Ba3Fe2TeO9Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f31bf4c1-e9db-47f6-8bb1-3e2353e715a0Symplectic Elements at OxfordElsevier2017Tang, YSena, RPAvdeev, MBattle, PDHunter, EC <p>A polycrystalline sample of Ba<sub>3</sub>Fe<sub>2</sub>TeO<sub>9</sub> having the 6H perovskite structure has been prepared in a solid-state reaction and studied by a combination of electron microscopy, Mössbauer spectroscopy, magnetometry, X-ray diffraction and neutron diffraction. Partial ordering of Fe<sup>3+</sup> and Te<sup>6+</sup> cations occurs over the six-coordinate sites; the corner-sharing octahedra are predominantly occupied by the former and the face-sharing octahedra by a 1:1 mixture of the two. On cooling through the temperature range 18 < T/K < 295 an increasing number of spins join an antiferromagnetic backbone running through the structure while the remainder show complex relaxation effects. At 3 K an antiferromagnetic phase and a spin glass coexist.</p> |
| spellingShingle | Tang, Y Sena, RP Avdeev, M Battle, PD Hunter, EC Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title | Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title_full | Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title_fullStr | Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title_full_unstemmed | Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title_short | Magnetic properties of the 6H Perovskite Ba3Fe2TeO9 |
| title_sort | magnetic properties of the 6h perovskite ba3fe2teo9 |
| work_keys_str_mv | AT tangy magneticpropertiesofthe6hperovskiteba3fe2teo9 AT senarp magneticpropertiesofthe6hperovskiteba3fe2teo9 AT avdeevm magneticpropertiesofthe6hperovskiteba3fe2teo9 AT battlepd magneticpropertiesofthe6hperovskiteba3fe2teo9 AT hunterec magneticpropertiesofthe6hperovskiteba3fe2teo9 |