THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION
It is shown using linear sweep and rotating-disc voltammetry that the reduction of the dye fluorescein at ca. pH 6 in aqueous solution proceeds via a DISP2 mechanism. In particular the rotating-disc measurements show voltammetric waves which display a shift in the half-wave potential with disc rotat...
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| Format: | Journal article |
| Language: | English |
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1988
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| _version_ | 1826304751196700672 |
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| author | Compton, R Mason, D Unwin, P |
| author_facet | Compton, R Mason, D Unwin, P |
| author_sort | Compton, R |
| collection | OXFORD |
| description | It is shown using linear sweep and rotating-disc voltammetry that the reduction of the dye fluorescein at ca. pH 6 in aqueous solution proceeds via a DISP2 mechanism. In particular the rotating-disc measurements show voltammetric waves which display a shift in the half-wave potential with disc rotation speed and which also analyse to give curved Tafel plots entirely in agreement with the behaviour predicted theoretically for a DISP2 process on the basis of a reaction layer treatment. |
| first_indexed | 2024-03-07T06:22:32Z |
| format | Journal article |
| id | oxford-uuid:f32d263e-792e-4bb9-93df-ac79acc6cda9 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:22:32Z |
| publishDate | 1988 |
| record_format | dspace |
| spelling | oxford-uuid:f32d263e-792e-4bb9-93df-ac79acc6cda92022-03-27T12:09:55ZTHE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTIONJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f32d263e-792e-4bb9-93df-ac79acc6cda9EnglishSymplectic Elements at Oxford1988Compton, RMason, DUnwin, PIt is shown using linear sweep and rotating-disc voltammetry that the reduction of the dye fluorescein at ca. pH 6 in aqueous solution proceeds via a DISP2 mechanism. In particular the rotating-disc measurements show voltammetric waves which display a shift in the half-wave potential with disc rotation speed and which also analyse to give curved Tafel plots entirely in agreement with the behaviour predicted theoretically for a DISP2 process on the basis of a reaction layer treatment. |
| spellingShingle | Compton, R Mason, D Unwin, P THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title | THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title_full | THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title_fullStr | THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title_full_unstemmed | THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title_short | THE REDUCTION OF FLUORESCEIN IN AQUEOUS-SOLUTION (AT PH-6) - A NEW DISP2 REACTION |
| title_sort | reduction of fluorescein in aqueous solution at ph 6 a new disp2 reaction |
| work_keys_str_mv | AT comptonr thereductionoffluoresceininaqueoussolutionatph6anewdisp2reaction AT masond thereductionoffluoresceininaqueoussolutionatph6anewdisp2reaction AT unwinp thereductionoffluoresceininaqueoussolutionatph6anewdisp2reaction AT comptonr reductionoffluoresceininaqueoussolutionatph6anewdisp2reaction AT masond reductionoffluoresceininaqueoussolutionatph6anewdisp2reaction AT unwinp reductionoffluoresceininaqueoussolutionatph6anewdisp2reaction |