Discovery of dark pH-dependent H+ migration in a [NiFe]-hydrogenase and its mechanistic relevance: mobilizing the hydrido ligand of the Ni-C intermediate

Discovery of dark pH-dependent H+ migration in a [NiFe]-hydrogenase and its mechanistic relevance: mobilizing the hydrido ligand of the Ni-C intermediate

<p>Despite extensive studies on [NiFe]-hydrogenases, the mechanism by which these enzymes produce and activate H<sub>2</sub> so efficiently remains unclear. A well-known EPR-active state produced under H<sub>2</sub> and known as Ni-C is assigned as a N...

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Bibliografiske detaljer
Main Authors:	Murphy, BJ, Hidalgo, R, Roessler, MM, Evans, RM, Ash, PA, Myers, WK, Vincent, KA, Armstrong, FA
Format:	Journal article
Sprog:	English
Udgivet:	American Chemical Society 2015

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