{Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach
We report the synthesis, structural characterisation andsolution-phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12-electron {Rh(PiBu 3) 2} + fragment. Crystal structures of this fragment with benzene, na...
| Main Authors: | , , , , , , , |
|---|---|
| Format: | Journal article |
| Language: | English |
| Published: |
2011
|
| _version_ | 1797103654687211520 |
|---|---|
| author | Woolf, A Chaplin, AB McGrady, J Alibadi, M Rees, N Draper, S Murphy, F Weller, A |
| author_facet | Woolf, A Chaplin, AB McGrady, J Alibadi, M Rees, N Draper, S Murphy, F Weller, A |
| author_sort | Woolf, A |
| collection | OXFORD |
| description | We report the synthesis, structural characterisation andsolution-phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12-electron {Rh(PiBu 3) 2} + fragment. Crystal structures of this fragment with benzene, naphthalene, anthracene, pyrene, triphenylene and coronene are described, alongside their solution NMR spectroscopic data. The ligands map out a systematic increase in size of the aromatic subunit, and represent an approach to the limiting case of coordination to a graphene surface. The solid-state and solution structures of a {Rh(COD)} + fragment coordinated to a hexa-peri-hexabenzocoronene are also reported. A range of polyaromatic hydrocarbons of increasing size (naphthalene through coronene) have been prepared and their solid-state and solution structures investigated. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA. |
| first_indexed | 2024-03-07T06:23:09Z |
| format | Journal article |
| id | oxford-uuid:f35ac2c9-f6c4-43c6-b5df-429154abda2f |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:23:09Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:f35ac2c9-f6c4-43c6-b5df-429154abda2f2022-03-27T12:11:29Z{Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental ApproachJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f35ac2c9-f6c4-43c6-b5df-429154abda2fEnglishSymplectic Elements at Oxford2011Woolf, AChaplin, ABMcGrady, JAlibadi, MRees, NDraper, SMurphy, FWeller, AWe report the synthesis, structural characterisation andsolution-phase dynamics of a series of polyaromatic hydrocarbon complexes of the 12-electron {Rh(PiBu 3) 2} + fragment. Crystal structures of this fragment with benzene, naphthalene, anthracene, pyrene, triphenylene and coronene are described, alongside their solution NMR spectroscopic data. The ligands map out a systematic increase in size of the aromatic subunit, and represent an approach to the limiting case of coordination to a graphene surface. The solid-state and solution structures of a {Rh(COD)} + fragment coordinated to a hexa-peri-hexabenzocoronene are also reported. A range of polyaromatic hydrocarbons of increasing size (naphthalene through coronene) have been prepared and their solid-state and solution structures investigated. Copyright © 2011 WILEY-VCH Verlag GmbH and Co. KGaA. |
| spellingShingle | Woolf, A Chaplin, AB McGrady, J Alibadi, M Rees, N Draper, S Murphy, F Weller, A {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title | {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title_full | {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title_fullStr | {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title_full_unstemmed | {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title_short | {Rh(PiBu(3))(2)}(+) Fragments Ligated to Arenes: From Benzene to Polyaromatic Hydrocarbons, Part I - An Experimental Approach |
| title_sort | rh pibu 3 2 fragments ligated to arenes from benzene to polyaromatic hydrocarbons part i an experimental approach |
| work_keys_str_mv | AT woolfa rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT chaplinab rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT mcgradyj rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT alibadim rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT reesn rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT drapers rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT murphyf rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach AT wellera rhpibu32fragmentsligatedtoarenesfrombenzenetopolyaromatichydrocarbonspartianexperimentalapproach |