Strong H...F hydrogen bonds as synthons in polymeric quantum magnets: structural, magnetic, and theoretical characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2.

Strong H...F hydrogen bonds as synthons in polymeric quantum magnets: structural, magnetic, and theoretical characterization of [Cu(HF2)(pyrazine)2]SbF6, [Cu2F(HF)(HF2)(pyrazine)4](SbF6)2, and [CuAg(H3F4)(pyrazine)5](SbF6)2.

Three Cu(2+)-containing coordination polymers were synthesized and characterized by experimental (X-ray diffraction, magnetic susceptibility, pulsed-field magnetization, heat capacity, and muon-spin relaxation) and electronic structure studies (quantum Monte Carlo simulations and density functional...

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Bibliographic Details
Main Authors: Manson, J, Schlueter, J, Funk, K, Southerland, H, Twamley, B, Lancaster, T, Blundell, S, Baker, P, Pratt, F, Singleton, J, McDonald, R, Goddard, P, Sengupta, P, Batista, C, Ding, L, Lee, C, Whangbo, M, Franke, I, Cox, S, Baines, C, Trial, D
Format: Journal article
Language:English
Published: 2009

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