Dramatic enhancement of intrinsic two-photon absorption in a conjugated porphyrin dimer

We report strong cooperative enhancement of simultaneous two-photon absorption cross section in a porphyrin dimer. The two-photon cross section, σ 2 = 6 × 10 -47 cm 4s/photon, corresponds to a 400-fold increase over the value me...

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Príomhchruthaitheoirí: Karotki, A, Drobizhev, M, Dzenis, Y, Taylor, P, Anderson, H, Rebane, A
Formáid: Journal article
Teanga:English
Foilsithe / Cruthaithe: 2004
Cur síos
Achoimre:We report strong cooperative enhancement of simultaneous two-photon absorption cross section in a porphyrin dimer. The two-photon cross section, σ 2 = 6 × 10 -47 cm 4s/photon, corresponds to a 400-fold increase over the value measured for the monomer, and is one of the largest ever obtained for organic chromophore of similar size.