Enantioselective total synthesis of (-)-xialenon A.

The first total synthesis of (-)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an alpha'-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described.

Номзүйн дэлгэрэнгүй
Үндсэн зохиолчид: Hodgson, D, Galano, J, Christlieb, M
Формат: Journal article
Хэл сонгох:English
Хэвлэсэн: 2002

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