Enantioselective total synthesis of (-)-xialenon A.

The first total synthesis of (-)-xialenon A (1) via conjugate allylation of a 1,5-cyclooctadiene-derived bicyclo[3.3.0]octenone 3 and an alpha'-hydroxylation on the more hinderd face of enone 9 using hypervalent iodine chemistry, is described.

书目详细资料
Main Authors:	Hodgson, D, Galano, J, Christlieb, M
格式:	Journal article
语言:	English
出版:	2002

相似书籍

Enantioselective total synthesis of (-)-xialenon A.
由: Hodgson, D, et al.
出版: (2002)

Synthesis of (-)-xialenon A by enantioselective alpha-deprotonation-rearrangement of a meso-epoxide
由: Hodgson, D, et al.
出版: (2003)

Enantioselective access to isoquinuclidines by tropenone desymmetrization and homoallylic radical rearrangement: synthesis of (+)-ibogamine.
由: Hodgson, D, et al.
出版: (2005)

Enantioselective total synthesis of (-)-deoxoapodine
由: Kang, Taek, et al.
出版: (2020)

Enantioselective total synthesis of (R)-(−)-complanine
由: Krystal A. D. Kamanos, et al.
出版: (2012-10-01)

A highly enantioselective total synthesis of (+)-goniodiol.
由: Tate, E, et al.
出版: (2006)

The enantioselective total synthesis of Sealutomicin C
由: Astle, S
出版: (2023)

Enantioselective Total Synthesis of (+)-Lyngbyabellin M
由: Rodrigo V. Pirovani, et al.
出版: (2015-05-01)

Enantioselective Total Synthesis of (−)-Acylfulvene and (−)- Irofulven
由: Movassaghi, Mohammad, et al.
出版: (2012)

Functionalised bicyclic alcohols by enantioselective alpha-deprotonation-rearrangement of meso-epoxides
由: Hodgson, D, et al.
出版: (2001)

Enantioselective desymmetrisation of an epoxytropinone for peduncularine synthesis
由: Shelton, RE, et al.
出版: (2020)

Catalytic enantioselective total synthesis of hodgkinsine B.
由: Snell, R, et al.
出版: (2011)

Enantioselective total Synthesis of the agelastatin and trigonoliimine alkaloids
由: Han, Sunkyu, 1982-
出版: (2012)

Convergent and Biomimetic Enantioselective Total Synthesis of (−)-Communesin F
由: Lathrop, Stephen, et al.
出版: (2018)

Concise and Enantioselective Total Synthesis of (−)-Mehranine, (−)-Methylenebismehranine, and Related
由: Mewald, Marius, et al.
出版: (2017)

Enantioselective alpha-deprotonation of epoxides.
由: Hodgson, D
出版: (2001)

Stereoselective total synthesis and enantioselective formal synthesis of the antineoplastic sesquiterpene quinone metachromin A
由: Almeida Wanda P., et al.
出版: (1999-01-01)

Enantioselective Total Synthesis of Multifidene, a Sex Pheromone of Brown Algae
由: Taiki Umezawa, et al.
出版: (2022-07-01)

Enantioselective synthesis of epoxides by alpha-deprotonation--electrophile trapping of achiral epoxides.
由: Hodgson, D, et al.
出版: (2003)

Enantioselective [4 + 2] cycloadditions of iminoacetonitriles : application to the total synthesis of (-)-quinolizidine 2071
由: Fontaine, Shaun D. (Shaun David)
出版: (2012)

Enantioselective desymmetrisation of achiral epoxides
由: Hodgson, D, et al.
出版: (1996)

A new and enantioselective indolizidine synthesis by meso-epoxide alpha-deprotonation-transannular N-C insertion
由: Hodgson, D, et al.
出版: (1999)

Synthesis and anticancer evaluation of agelastatin alkaloid derivatives and enantioselective total synthesis of aspidosperma alkaloids
由: Antropow, Alyssa Hope
出版: (2018)

Enantioselective total synthesis of (+)-incargranine A enabled by bifunctional iminophosphorane and iridium catalysis
由: Miller, AAM, et al.
出版: (2023)

A new organocatalytic desymmetrization reaction enables the enantioselective total synthesis of madangamine E
由: Shiomi, S, et al.
出版: (2022)

HIGHLY ENANTIOSELECTIVE REARRANGEMENT OF A MESO-EPOXIDE TO AN ALLYL ALCOHOL FOR CARBOCYCLIC NUCLEOSIDE SYNTHESIS - AN INTERNAL ALKOXIDE EFFECT
由: Hodgson, D, et al.
出版: (1994)

Enantioselective rearrangement of exo-norbornene oxide to nortricyclanol
由: Hodgson, D, et al.
出版: (1996)

Enantioselective alpha-deprotonation-rearrangement of meso-epoxides
由: Hodgson, D, et al.
出版: (1996)

Enantioselective total synthesis of lycoposerramine congeners through late-stage nitrogen deletion
由: Kenta Yokoi, et al.
出版: (2025-02-01)

Enantioselective total synthesis of (‒)-lucidumone enabled by tandem prins cyclization/cycloetherification sequence
由: Xian-Zhang Liao, et al.
出版: (2024-03-01)

Cross-Metathesis of Methallyl Halides: Concise Enantioselective Formal Total Synthesis of (–)-Presphaerene
由: Suresh Mandava, et al.
出版: (2020-06-01)

ORGN 743-Palladium-catalyzed enantioselective desymmetrization for the total synthesis of hodgkinsine and related structures
由: Durbin, M, et al.
出版: (2006)

From Racemic to Enantioselective Total Synthesis of Trigonoliimines via Development of an Organocatalytic Enantioselective Michael Addition of ?-Aryl-?-isocyanoacetate to Vinyl Phenyl Selenone
由: Thomas Buyck, et al.
出版: (2014-04-01)

Directed Palladium Catalyzed Acetoxylation of Indolines and Enantioselective Total Synthesis of (–)-Voacinol and (–)-Voacandimine C
由: Flynn, Kristen M.
出版: (2022)

Bioinspired total synthesis of katsumadain A by organocatalytic enantioselective 1,4-conjugate addition
由: Yongguang Wang, et al.
出版: (2013-08-01)

Enantioselective Synthesis of Sealutomicin C
由: Astle, SM, et al.
出版: (2024)

The enantioselective synthesis of (S)-(+)-mianserin and (S)-(+)-epinastine
由: Piotr Roszkowski, et al.
出版: (2015-08-01)

Carbamate-directed hydroboration: Enantioselective synthesis of the excitatory amino acid 1-aminocyclopentane-1,3-dicarboxylic acid
由: Hodgson, D, et al.
出版: (1998)

Enantioselective synthesis of cis-hydrobenzofurans bearing all-carbon quaternary stereocenters and application to total synthesis of (‒)-morphine
由: Qing Zhang, et al.
出版: (2019-06-01)