σ-Alane complexes of chromium, tungsten, and manganese.
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ(1) σ-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related κ(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemica...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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| _version_ | 1826304960187334656 |
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| author | Riddlestone, I Edmonds, S Kaufman, P Urbano, J Bates, J Kelly, M Thompson, A Taylor, R Aldridge, S |
| author_facet | Riddlestone, I Edmonds, S Kaufman, P Urbano, J Bates, J Kelly, M Thompson, A Taylor, R Aldridge, S |
| author_sort | Riddlestone, I |
| collection | OXFORD |
| description | Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ(1) σ-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related κ(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as σ-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes. |
| first_indexed | 2024-03-07T06:25:38Z |
| format | Journal article |
| id | oxford-uuid:f432f578-abf8-4862-88fb-007a6d44114e |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:25:38Z |
| publishDate | 2012 |
| record_format | dspace |
| spelling | oxford-uuid:f432f578-abf8-4862-88fb-007a6d44114e2022-03-27T12:17:56Zσ-Alane complexes of chromium, tungsten, and manganese.Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f432f578-abf8-4862-88fb-007a6d44114eEnglishSymplectic Elements at Oxford2012Riddlestone, IEdmonds, SKaufman, PUrbano, JBates, JKelly, MThompson, ATaylor, RAldridge, SPhotolytic ligand displacement and salt metathesis routes have been exploited to give access to κ(1) σ-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related κ(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemical studies are consistent with the alane ligands acting predominantly as σ-donors, with the resulting binding energies calculated to be marginally greater than those found for related dihydrogen complexes. |
| spellingShingle | Riddlestone, I Edmonds, S Kaufman, P Urbano, J Bates, J Kelly, M Thompson, A Taylor, R Aldridge, S σ-Alane complexes of chromium, tungsten, and manganese. |
| title | σ-Alane complexes of chromium, tungsten, and manganese. |
| title_full | σ-Alane complexes of chromium, tungsten, and manganese. |
| title_fullStr | σ-Alane complexes of chromium, tungsten, and manganese. |
| title_full_unstemmed | σ-Alane complexes of chromium, tungsten, and manganese. |
| title_short | σ-Alane complexes of chromium, tungsten, and manganese. |
| title_sort | σ alane complexes of chromium tungsten and manganese |
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