σ-Alane complexes of chromium, tungsten, and manganese.
Photolytic ligand displacement and salt metathesis routes have been exploited to give access to κ(1) σ-alane complexes featuring Al-H bonds bound to [W(CO)(5)] and [Cp'Mn(CO)(2)] fragments, together with a related κ(2) complex of [Cr(CO)(4)]. Spectroscopic, crystallographic, and quantum chemica...
| Main Authors: | , , , , , , , , |
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| Format: | Journal article |
| Language: | English |
| Published: |
2012
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