Mechanical properties of colloidal crystals at fluid interfaces

We characterise the local mechanical properties of two-dimensional colloidal crystals with hexagonal symmetry assembled at the flat interface between oil and water. Our experiments elucidate the conditions under which the material behaves isotropically, as opposed to those where the microstructure p...

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Main Authors: Buttinoni, I, Dullens, RPA
Format: Journal article
Language:English
Published: IOP Publishing 2021
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author Buttinoni, I
Dullens, RPA
author_facet Buttinoni, I
Dullens, RPA
author_sort Buttinoni, I
collection OXFORD
description We characterise the local mechanical properties of two-dimensional colloidal crystals with hexagonal symmetry assembled at the flat interface between oil and water. Our experiments elucidate the conditions under which the material behaves isotropically, as opposed to those where the microstructure plays a major role. Brownian fluctuations are used to extract the stiffness of the lattice under the continuum approximation, whereas at larger displacements, obtained by optically driving one particle through the structure, the mechanical resistance of the lattice depends on both the area fraction and the direction of the applied force. Remarkably, the minimum resistance does not necessarily correspond to a probe being driven between neighbours, i.e. at 30° with respect to the crystal axes.
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spelling oxford-uuid:f45a4cb5-70dc-42ea-b3f1-3d4636a057772022-03-27T12:19:12ZMechanical properties of colloidal crystals at fluid interfacesJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f45a4cb5-70dc-42ea-b3f1-3d4636a05777EnglishSymplectic ElementsIOP Publishing2021Buttinoni, IDullens, RPAWe characterise the local mechanical properties of two-dimensional colloidal crystals with hexagonal symmetry assembled at the flat interface between oil and water. Our experiments elucidate the conditions under which the material behaves isotropically, as opposed to those where the microstructure plays a major role. Brownian fluctuations are used to extract the stiffness of the lattice under the continuum approximation, whereas at larger displacements, obtained by optically driving one particle through the structure, the mechanical resistance of the lattice depends on both the area fraction and the direction of the applied force. Remarkably, the minimum resistance does not necessarily correspond to a probe being driven between neighbours, i.e. at 30° with respect to the crystal axes.
spellingShingle Buttinoni, I
Dullens, RPA
Mechanical properties of colloidal crystals at fluid interfaces
title Mechanical properties of colloidal crystals at fluid interfaces
title_full Mechanical properties of colloidal crystals at fluid interfaces
title_fullStr Mechanical properties of colloidal crystals at fluid interfaces
title_full_unstemmed Mechanical properties of colloidal crystals at fluid interfaces
title_short Mechanical properties of colloidal crystals at fluid interfaces
title_sort mechanical properties of colloidal crystals at fluid interfaces
work_keys_str_mv AT buttinonii mechanicalpropertiesofcolloidalcrystalsatfluidinterfaces
AT dullensrpa mechanicalpropertiesofcolloidalcrystalsatfluidinterfaces