The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?
Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion w...
| Main Authors: | , , , |
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| Format: | Journal article |
| Language: | English |
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2011
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| _version_ | 1797103916957040640 |
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| author | Knapp, C Large, J Rees, N Goicoechea, J |
| author_facet | Knapp, C Large, J Rees, N Goicoechea, J |
| author_sort | Knapp, C |
| collection | OXFORD |
| description | Reaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted. |
| first_indexed | 2024-03-07T06:26:50Z |
| format | Journal article |
| id | oxford-uuid:f496eaa2-d129-4c3d-8106-e454ec965280 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:26:50Z |
| publishDate | 2011 |
| record_format | dspace |
| spelling | oxford-uuid:f496eaa2-d129-4c3d-8106-e454ec9652802022-03-27T12:20:56ZThe bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene?Journal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f496eaa2-d129-4c3d-8106-e454ec965280EnglishSymplectic Elements at Oxford2011Knapp, CLarge, JRees, NGoicoechea, JReaction of K(3)P(7), FeCl(2), [NH(4)][B(C(6)H(5))(4)] and 2,2,2-crypt yielded the unprecedented cluster dianion [Fe(HP(7))(2)](2-). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on the dianion were also conducted. |
| spellingShingle | Knapp, C Large, J Rees, N Goicoechea, J The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title | The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title_full | The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title_fullStr | The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title_full_unstemmed | The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title_short | The bis(hydrogenheptaphosphide)iron(II) dianion: a Zintl ion analogue of ferrocene? |
| title_sort | bis hydrogenheptaphosphide iron ii dianion a zintl ion analogue of ferrocene |
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