An isolable phosphaethynolato-borane and its reactivity

The synthesis and characterization of a stable phosphaethynolato-borane, [B]OCP (1, [B] = N,N'-bis(2,6-diisopropylphenyl)-2,3-dihydro-1H-1,3,2-diazaboryl), is described. The increased triple bond character of the P-C bond in 1 relative to the free ion (PCO-) is probed in a series of reactivity...

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Bibliographic Details
Main Authors: Wilson, D, Hinz, A, Goicoechea, JM
Format: Journal article
Language:English
Published: Wiley 2018