HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES
Vapour phase He (II) photoelectron spectra of the thallium (I) and indium (I) halides MX (X = Cl, Br, I) are reported and compared with He (I) data. The additional structure in He (II) spectra is due largely to ionization of "inner" d electrons; the detail can be understood in terms of a w...
| Main Authors: | , |
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| פורמט: | Journal article |
| שפה: | English |
| יצא לאור: |
1978
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| _version_ | 1826305154634219520 |
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| author | Egdell, R Orchard, A |
| author_facet | Egdell, R Orchard, A |
| author_sort | Egdell, R |
| collection | OXFORD |
| description | Vapour phase He (II) photoelectron spectra of the thallium (I) and indium (I) halides MX (X = Cl, Br, I) are reported and compared with He (I) data. The additional structure in He (II) spectra is due largely to ionization of "inner" d electrons; the detail can be understood in terms of a weak-field perturbation of 2D5/2 and 2D 3/2 final states associated with a d9 configuration at the metal ion. However, the spectrum of TICI contains certain extra features which probably represent many-electron (or shake-up) processes. |
| first_indexed | 2024-03-07T06:28:34Z |
| format | Journal article |
| id | oxford-uuid:f5298cdc-c7f6-4317-b73c-df688f23c430 |
| institution | University of Oxford |
| language | English |
| last_indexed | 2024-03-07T06:28:34Z |
| publishDate | 1978 |
| record_format | dspace |
| spelling | oxford-uuid:f5298cdc-c7f6-4317-b73c-df688f23c4302022-03-27T12:25:23ZHE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDESJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f5298cdc-c7f6-4317-b73c-df688f23c430EnglishSymplectic Elements at Oxford1978Egdell, ROrchard, AVapour phase He (II) photoelectron spectra of the thallium (I) and indium (I) halides MX (X = Cl, Br, I) are reported and compared with He (I) data. The additional structure in He (II) spectra is due largely to ionization of "inner" d electrons; the detail can be understood in terms of a weak-field perturbation of 2D5/2 and 2D 3/2 final states associated with a d9 configuration at the metal ion. However, the spectrum of TICI contains certain extra features which probably represent many-electron (or shake-up) processes. |
| spellingShingle | Egdell, R Orchard, A HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title | HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title_full | HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title_fullStr | HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title_full_unstemmed | HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title_short | HE(II) PHOTOELECTRON-SPECTRA OF INDIUM(I) AND THALLIUM(I) HALIDES |
| title_sort | he ii photoelectron spectra of indium i and thallium i halides |
| work_keys_str_mv | AT egdellr heiiphotoelectronspectraofindiumiandthalliumihalides AT orcharda heiiphotoelectronspectraofindiumiandthalliumihalides |