Stereodynamical control of a quantum scattering resonance in cold molecular collisions

<p>Cold collisions of light molecules are often dominated by a single partial wave resonance. For the rotational quenching of HD (<em>v</em> = 1, <em>j</em> = 2) by collisions with ground state <em>para</em>-H<sub>2</sub>, the process is dominate...

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Main Authors: Jambrina, PG, Croft, JFE, Guo, H, Brouard, M, Balakrishnan, N, Aoiz, FJ
Format: Journal article
Language:English
Published: American Physical Society 2019
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author Jambrina, PG
Croft, JFE
Guo, H
Brouard, M
Balakrishnan, N
Aoiz, FJ
author_facet Jambrina, PG
Croft, JFE
Guo, H
Brouard, M
Balakrishnan, N
Aoiz, FJ
author_sort Jambrina, PG
collection OXFORD
description <p>Cold collisions of light molecules are often dominated by a single partial wave resonance. For the rotational quenching of HD (<em>v</em> = 1, <em>j</em> = 2) by collisions with ground state <em>para</em>-H<sub>2</sub>, the process is dominated by a single <em>L</em> = 2 partial wave resonance centered around 0.1 K. Here, we show that this resonance can be switched on or off simply by appropriate alignment of the HD rotational angular momentum relative to the initial velocity vector, thereby enabling complete control of the collision outcome.</p>
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spelling oxford-uuid:f597ba3a-fb7e-40a4-b4d7-364bb5726f932022-03-27T12:28:27ZStereodynamical control of a quantum scattering resonance in cold molecular collisionsJournal articlehttp://purl.org/coar/resource_type/c_dcae04bcuuid:f597ba3a-fb7e-40a4-b4d7-364bb5726f93EnglishSymplectic Elements at OxfordAmerican Physical Society2019Jambrina, PGCroft, JFEGuo, HBrouard, MBalakrishnan, NAoiz, FJ<p>Cold collisions of light molecules are often dominated by a single partial wave resonance. For the rotational quenching of HD (<em>v</em> = 1, <em>j</em> = 2) by collisions with ground state <em>para</em>-H<sub>2</sub>, the process is dominated by a single <em>L</em> = 2 partial wave resonance centered around 0.1 K. Here, we show that this resonance can be switched on or off simply by appropriate alignment of the HD rotational angular momentum relative to the initial velocity vector, thereby enabling complete control of the collision outcome.</p>
spellingShingle Jambrina, PG
Croft, JFE
Guo, H
Brouard, M
Balakrishnan, N
Aoiz, FJ
Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title_full Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title_fullStr Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title_full_unstemmed Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title_short Stereodynamical control of a quantum scattering resonance in cold molecular collisions
title_sort stereodynamical control of a quantum scattering resonance in cold molecular collisions
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AT croftjfe stereodynamicalcontrolofaquantumscatteringresonanceincoldmolecularcollisions
AT guoh stereodynamicalcontrolofaquantumscatteringresonanceincoldmolecularcollisions
AT brouardm stereodynamicalcontrolofaquantumscatteringresonanceincoldmolecularcollisions
AT balakrishnann stereodynamicalcontrolofaquantumscatteringresonanceincoldmolecularcollisions
AT aoizfj stereodynamicalcontrolofaquantumscatteringresonanceincoldmolecularcollisions